Characteristic Conformation of Mosher’s Amide Elucidated Using the Cambridge Structural Database

Characteristic Conformation of Mosher’s Amide Elucidated Using the Cambridge Structural Database

Conformations of the crystalline 3,3,3-trifluoro-2-methoxy-2-phenylpropanamide derivatives (MTPA amides) deposited in the Cambridge Structural Database (CSD) were examined statistically as Racid-enantiomers. The majority of dihedral angles (48/58, ca. 83%) of the amide carbonyl groups and the triflu...

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Bibliographic Details
Main Authors: Akio Ichikawa, Hiroshi Ono, Yuji Mikata
Format: Article
Language:English
Published: MDPI AG 2015-07-01
Series:Molecules
Subjects:
chiral recognition
chirality
crystal engineering
Mosher’s method
MTPA
Online Access:http://www.mdpi.com/1420-3049/20/7/12880

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