Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> Nanofibers
Titanium dioxide (TiO<sub>2</sub>) nanomaterials have been ubiquitously investigated as a photocatalyst for organic contaminant treatment in wastewater due to their exemplary semiconductor properties. However, their huge band gap remains a barrier for visible light absorption, limiting t...
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doaj-474033f7a00a418bace4c719c7492a1b2021-03-28T00:01:44ZengMDPI AGNanomaterials2079-49912021-03-011185685610.3390/nano11040856Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> NanofibersJerry Zhi Xiong Heng0Karen Yuanting Tang1Michelle D. Regulacio2Ming Lin3Xian Jun Loh4Zibiao Li5Enyi Ye6Institute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore 138634, SingaporeInstitute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore 138634, SingaporeInstitute of Chemistry, University of the Philippines Diliman, Quezon City 1101, PhilippinesInstitute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore 138634, SingaporeInstitute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore 138634, SingaporeInstitute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore 138634, SingaporeInstitute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore 138634, SingaporeTitanium dioxide (TiO<sub>2</sub>) nanomaterials have been ubiquitously investigated as a photocatalyst for organic contaminant treatment in wastewater due to their exemplary semiconductor properties. However, their huge band gap remains a barrier for visible light absorption, limiting their utility in practical applications. The incorporation of noble metals in the TiO<sub>2</sub> scaffold would help mitigate the problem via plasmonic resonance enhancements. Silver (Ag) is the chosen noble metal as it is relatively cheap and has great plasmonic effects. In this study, the use of electrospun Ag-embedded TiO<sub>2</sub> nanofibers as a photocatalyst is shown to be effective in decomposing rhodamine B and methyl orange dyes under a solar simulator in 3 h, which is more efficacious as opposed to pristine TiO<sub>2</sub> nanofibers. This showcases the potential of a simple and economic wastewater treatment system for the removal of organic pollutants.https://www.mdpi.com/2079-4991/11/4/856photocatalytic oxidationdegradation of organic dye pollutantslocalized surface plasmon resonance effectheterogenous catalysishybrid nanocompositesmesoporous TiO<sub>2</sub> |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Jerry Zhi Xiong Heng Karen Yuanting Tang Michelle D. Regulacio Ming Lin Xian Jun Loh Zibiao Li Enyi Ye |
spellingShingle |
Jerry Zhi Xiong Heng Karen Yuanting Tang Michelle D. Regulacio Ming Lin Xian Jun Loh Zibiao Li Enyi Ye Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> Nanofibers Nanomaterials photocatalytic oxidation degradation of organic dye pollutants localized surface plasmon resonance effect heterogenous catalysis hybrid nanocomposites mesoporous TiO<sub>2</sub> |
author_facet |
Jerry Zhi Xiong Heng Karen Yuanting Tang Michelle D. Regulacio Ming Lin Xian Jun Loh Zibiao Li Enyi Ye |
author_sort |
Jerry Zhi Xiong Heng |
title |
Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> Nanofibers |
title_short |
Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> Nanofibers |
title_full |
Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> Nanofibers |
title_fullStr |
Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> Nanofibers |
title_full_unstemmed |
Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> Nanofibers |
title_sort |
solar-powered photodegradation of pollutant dyes using silver-embedded porous tio<sub>2</sub> nanofibers |
publisher |
MDPI AG |
series |
Nanomaterials |
issn |
2079-4991 |
publishDate |
2021-03-01 |
description |
Titanium dioxide (TiO<sub>2</sub>) nanomaterials have been ubiquitously investigated as a photocatalyst for organic contaminant treatment in wastewater due to their exemplary semiconductor properties. However, their huge band gap remains a barrier for visible light absorption, limiting their utility in practical applications. The incorporation of noble metals in the TiO<sub>2</sub> scaffold would help mitigate the problem via plasmonic resonance enhancements. Silver (Ag) is the chosen noble metal as it is relatively cheap and has great plasmonic effects. In this study, the use of electrospun Ag-embedded TiO<sub>2</sub> nanofibers as a photocatalyst is shown to be effective in decomposing rhodamine B and methyl orange dyes under a solar simulator in 3 h, which is more efficacious as opposed to pristine TiO<sub>2</sub> nanofibers. This showcases the potential of a simple and economic wastewater treatment system for the removal of organic pollutants. |
topic |
photocatalytic oxidation degradation of organic dye pollutants localized surface plasmon resonance effect heterogenous catalysis hybrid nanocomposites mesoporous TiO<sub>2</sub> |
url |
https://www.mdpi.com/2079-4991/11/4/856 |
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