Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> Nanofibers

Titanium dioxide (TiO<sub>2</sub>) nanomaterials have been ubiquitously investigated as a photocatalyst for organic contaminant treatment in wastewater due to their exemplary semiconductor properties. However, their huge band gap remains a barrier for visible light absorption, limiting t...

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Main Authors: Jerry Zhi Xiong Heng, Karen Yuanting Tang, Michelle D. Regulacio, Ming Lin, Xian Jun Loh, Zibiao Li, Enyi Ye
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/11/4/856
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spelling doaj-474033f7a00a418bace4c719c7492a1b2021-03-28T00:01:44ZengMDPI AGNanomaterials2079-49912021-03-011185685610.3390/nano11040856Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> NanofibersJerry Zhi Xiong Heng0Karen Yuanting Tang1Michelle D. Regulacio2Ming Lin3Xian Jun Loh4Zibiao Li5Enyi Ye6Institute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore 138634, SingaporeInstitute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore 138634, SingaporeInstitute of Chemistry, University of the Philippines Diliman, Quezon City 1101, PhilippinesInstitute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore 138634, SingaporeInstitute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore 138634, SingaporeInstitute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore 138634, SingaporeInstitute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore 138634, SingaporeTitanium dioxide (TiO<sub>2</sub>) nanomaterials have been ubiquitously investigated as a photocatalyst for organic contaminant treatment in wastewater due to their exemplary semiconductor properties. However, their huge band gap remains a barrier for visible light absorption, limiting their utility in practical applications. The incorporation of noble metals in the TiO<sub>2</sub> scaffold would help mitigate the problem via plasmonic resonance enhancements. Silver (Ag) is the chosen noble metal as it is relatively cheap and has great plasmonic effects. In this study, the use of electrospun Ag-embedded TiO<sub>2</sub> nanofibers as a photocatalyst is shown to be effective in decomposing rhodamine B and methyl orange dyes under a solar simulator in 3 h, which is more efficacious as opposed to pristine TiO<sub>2</sub> nanofibers. This showcases the potential of a simple and economic wastewater treatment system for the removal of organic pollutants.https://www.mdpi.com/2079-4991/11/4/856photocatalytic oxidationdegradation of organic dye pollutantslocalized surface plasmon resonance effectheterogenous catalysishybrid nanocompositesmesoporous TiO<sub>2</sub>
collection DOAJ
language English
format Article
sources DOAJ
author Jerry Zhi Xiong Heng
Karen Yuanting Tang
Michelle D. Regulacio
Ming Lin
Xian Jun Loh
Zibiao Li
Enyi Ye
spellingShingle Jerry Zhi Xiong Heng
Karen Yuanting Tang
Michelle D. Regulacio
Ming Lin
Xian Jun Loh
Zibiao Li
Enyi Ye
Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> Nanofibers
Nanomaterials
photocatalytic oxidation
degradation of organic dye pollutants
localized surface plasmon resonance effect
heterogenous catalysis
hybrid nanocomposites
mesoporous TiO<sub>2</sub>
author_facet Jerry Zhi Xiong Heng
Karen Yuanting Tang
Michelle D. Regulacio
Ming Lin
Xian Jun Loh
Zibiao Li
Enyi Ye
author_sort Jerry Zhi Xiong Heng
title Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> Nanofibers
title_short Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> Nanofibers
title_full Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> Nanofibers
title_fullStr Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> Nanofibers
title_full_unstemmed Solar-Powered Photodegradation of Pollutant Dyes Using Silver-Embedded Porous TiO<sub>2</sub> Nanofibers
title_sort solar-powered photodegradation of pollutant dyes using silver-embedded porous tio<sub>2</sub> nanofibers
publisher MDPI AG
series Nanomaterials
issn 2079-4991
publishDate 2021-03-01
description Titanium dioxide (TiO<sub>2</sub>) nanomaterials have been ubiquitously investigated as a photocatalyst for organic contaminant treatment in wastewater due to their exemplary semiconductor properties. However, their huge band gap remains a barrier for visible light absorption, limiting their utility in practical applications. The incorporation of noble metals in the TiO<sub>2</sub> scaffold would help mitigate the problem via plasmonic resonance enhancements. Silver (Ag) is the chosen noble metal as it is relatively cheap and has great plasmonic effects. In this study, the use of electrospun Ag-embedded TiO<sub>2</sub> nanofibers as a photocatalyst is shown to be effective in decomposing rhodamine B and methyl orange dyes under a solar simulator in 3 h, which is more efficacious as opposed to pristine TiO<sub>2</sub> nanofibers. This showcases the potential of a simple and economic wastewater treatment system for the removal of organic pollutants.
topic photocatalytic oxidation
degradation of organic dye pollutants
localized surface plasmon resonance effect
heterogenous catalysis
hybrid nanocomposites
mesoporous TiO<sub>2</sub>
url https://www.mdpi.com/2079-4991/11/4/856
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