Treatment of Organic Matter and Tetracycline in Water by Using Constructed Wetlands and Photocatalysis

In this study, the ability of a bench-scale simulated constructed wetland (CW) to remove organic matter (OM) and tetracycline (TC) from water was examined. The performance of CW was evaluated by varying the initial concentrations of the target compounds and the hydraulic retention times (HRTs). Find...

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Main Authors: Hong Thi Thu Nguyen, How-Ran Chao, Kuan-Chung Chen
Format: Article
Language:English
Published: MDPI AG 2019-06-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/9/13/2680
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spelling doaj-471bae35bcd344e390e6e06b08dcb0c92020-11-25T00:48:18ZengMDPI AGApplied Sciences2076-34172019-06-01913268010.3390/app9132680app9132680Treatment of Organic Matter and Tetracycline in Water by Using Constructed Wetlands and PhotocatalysisHong Thi Thu Nguyen0How-Ran Chao1Kuan-Chung Chen2Department of Tropical Agriculture and International Cooperation, National Pingtung University of Science and Technology, Pingtung 91201, TaiwanDepartment of Environmental Science and Engineering, National Pingtung University of Science and Technology, Pingtung 91201, TaiwanDepartment of Environmental Science and Engineering, National Pingtung University of Science and Technology, Pingtung 91201, TaiwanIn this study, the ability of a bench-scale simulated constructed wetland (CW) to remove organic matter (OM) and tetracycline (TC) from water was examined. The performance of CW was evaluated by varying the initial concentrations of the target compounds and the hydraulic retention times (HRTs). Findings showed that OM removal efficiencies were 55.2&#8722;80.8%, 28.1&#8722;71.9% and 72.1&#8722;79.7% for ultraviolet absorbance at 254 nm (UV-254), dissolved organic carbon (DOC) and soluble chemical oxygen demand (sCOD) respectively, under 1 day-HRT, whereas higher initial DOC concentration achieved better removal efficiencies. Changing from 1 day-HRT to 2 day-HRT, the removal efficiency of OMs remained practically unchanged, while that of NH<sub>3</sub>-N increased considerably, from 61.7% to 73.0%, implying that the removal of ammonia in CW needs a longer time for complete treatment. CW also showed an excellent performance in removing TC, especially in the first two hours of operation through the absorption process. In addition, the findings from this research revealed an improvement in effluent water quality when photocatalysis (TiO<sub>2</sub>/&#945;-Al<sub>2</sub>O<sub>3</sub>, with ultraviolet A (UVA) irradiation) was used as the post-treatment following CW, presented by the increase in removal efficiency of OMs of the combined system compared to that of CW alone. This study points to the possible and promising application of the low-cost water treatment system for dealing with OMs and TC in water.https://www.mdpi.com/2076-3417/9/13/2680constructed wetlandsorganic mattertetracyclineremoval efficiencyphotocatalysiswater quality
collection DOAJ
language English
format Article
sources DOAJ
author Hong Thi Thu Nguyen
How-Ran Chao
Kuan-Chung Chen
spellingShingle Hong Thi Thu Nguyen
How-Ran Chao
Kuan-Chung Chen
Treatment of Organic Matter and Tetracycline in Water by Using Constructed Wetlands and Photocatalysis
Applied Sciences
constructed wetlands
organic matter
tetracycline
removal efficiency
photocatalysis
water quality
author_facet Hong Thi Thu Nguyen
How-Ran Chao
Kuan-Chung Chen
author_sort Hong Thi Thu Nguyen
title Treatment of Organic Matter and Tetracycline in Water by Using Constructed Wetlands and Photocatalysis
title_short Treatment of Organic Matter and Tetracycline in Water by Using Constructed Wetlands and Photocatalysis
title_full Treatment of Organic Matter and Tetracycline in Water by Using Constructed Wetlands and Photocatalysis
title_fullStr Treatment of Organic Matter and Tetracycline in Water by Using Constructed Wetlands and Photocatalysis
title_full_unstemmed Treatment of Organic Matter and Tetracycline in Water by Using Constructed Wetlands and Photocatalysis
title_sort treatment of organic matter and tetracycline in water by using constructed wetlands and photocatalysis
publisher MDPI AG
series Applied Sciences
issn 2076-3417
publishDate 2019-06-01
description In this study, the ability of a bench-scale simulated constructed wetland (CW) to remove organic matter (OM) and tetracycline (TC) from water was examined. The performance of CW was evaluated by varying the initial concentrations of the target compounds and the hydraulic retention times (HRTs). Findings showed that OM removal efficiencies were 55.2&#8722;80.8%, 28.1&#8722;71.9% and 72.1&#8722;79.7% for ultraviolet absorbance at 254 nm (UV-254), dissolved organic carbon (DOC) and soluble chemical oxygen demand (sCOD) respectively, under 1 day-HRT, whereas higher initial DOC concentration achieved better removal efficiencies. Changing from 1 day-HRT to 2 day-HRT, the removal efficiency of OMs remained practically unchanged, while that of NH<sub>3</sub>-N increased considerably, from 61.7% to 73.0%, implying that the removal of ammonia in CW needs a longer time for complete treatment. CW also showed an excellent performance in removing TC, especially in the first two hours of operation through the absorption process. In addition, the findings from this research revealed an improvement in effluent water quality when photocatalysis (TiO<sub>2</sub>/&#945;-Al<sub>2</sub>O<sub>3</sub>, with ultraviolet A (UVA) irradiation) was used as the post-treatment following CW, presented by the increase in removal efficiency of OMs of the combined system compared to that of CW alone. This study points to the possible and promising application of the low-cost water treatment system for dealing with OMs and TC in water.
topic constructed wetlands
organic matter
tetracycline
removal efficiency
photocatalysis
water quality
url https://www.mdpi.com/2076-3417/9/13/2680
work_keys_str_mv AT hongthithunguyen treatmentoforganicmatterandtetracyclineinwaterbyusingconstructedwetlandsandphotocatalysis
AT howranchao treatmentoforganicmatterandtetracyclineinwaterbyusingconstructedwetlandsandphotocatalysis
AT kuanchungchen treatmentoforganicmatterandtetracyclineinwaterbyusingconstructedwetlandsandphotocatalysis
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