Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics

Organohalides are widely used as synthetic precursors and target products, but for various halogenation reactions there is a need for effective catalysts to activate commercially available haleniums. Here, the authors report that TEMPO and its derivatives are active catalysts for electrophilic halog...

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Main Authors:	Weijin Wang, Xinyao Li, Xiaoxue Yang, Lingsheng Ai, Zhiwen Gong, Ning Jiao, Song Song
Format:	Article
Language:	English
Published:	Nature Publishing Group 2021-06-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-021-24174-w

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spelling	doaj-467a14265b2746ddaa418cf930f0abee2021-06-27T11:13:41ZengNature Publishing GroupNature Communications2041-17232021-06-0112111010.1038/s41467-021-24174-wOxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromaticsWeijin Wang0Xinyao Li1Xiaoxue Yang2Lingsheng Ai3Zhiwen Gong4Ning Jiao5Song Song6State Key Laboratory of Natural and Biomimetic Drugs, Peking UniversityState Key Laboratory of Natural and Biomimetic Drugs, Peking UniversityState Key Laboratory of Natural and Biomimetic Drugs, Peking UniversityState Key Laboratory of Natural and Biomimetic Drugs, Peking UniversityState Key Laboratory of Natural and Biomimetic Drugs, Peking UniversityState Key Laboratory of Natural and Biomimetic Drugs, Peking UniversityState Key Laboratory of Natural and Biomimetic Drugs, Peking UniversityOrganohalides are widely used as synthetic precursors and target products, but for various halogenation reactions there is a need for effective catalysts to activate commercially available haleniums. Here, the authors report that TEMPO and its derivatives are active catalysts for electrophilic halogenation of olefins, alkynes and aromatics, under mild reaction conditions and with good functional group tolerance.https://doi.org/10.1038/s41467-021-24174-w
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Weijin Wang Xinyao Li Xiaoxue Yang Lingsheng Ai Zhiwen Gong Ning Jiao Song Song
spellingShingle	Weijin Wang Xinyao Li Xiaoxue Yang Lingsheng Ai Zhiwen Gong Ning Jiao Song Song Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics Nature Communications
author_facet	Weijin Wang Xinyao Li Xiaoxue Yang Lingsheng Ai Zhiwen Gong Ning Jiao Song Song
author_sort	Weijin Wang
title	Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics
title_short	Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics
title_full	Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics
title_fullStr	Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics
title_full_unstemmed	Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics
title_sort	oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2021-06-01
description	Organohalides are widely used as synthetic precursors and target products, but for various halogenation reactions there is a need for effective catalysts to activate commercially available haleniums. Here, the authors report that TEMPO and its derivatives are active catalysts for electrophilic halogenation of olefins, alkynes and aromatics, under mild reaction conditions and with good functional group tolerance.
url	https://doi.org/10.1038/s41467-021-24174-w
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Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics

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