Potentiometric Control of Metal Concentration for Chelation Kinetics of Modified Polyimide Films

Interaction of modified polyimide films with agrentium nitrate solutions of various concentrations was studied. Sorption of Ag ions by films is divided into three steps: formation of Ag ion layer on the border of film surface; diffusion inside the films; and final saturation of film by Ag ions. The...

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Main Authors: Juldyz Akhmetova, Olga Moisseyevich, Andrey Kurbatov, Tleuken Akhmetov, Saule Kudaikulova, Bulat Zhubanov, Marc J.M. Abadie
Format: Article
Language:English
Published: al-Farabi Kazakh National University 2004-03-01
Series:Eurasian Chemico-Technological Journal 
Online Access:http://ect-journal.kz/index.php/ectj/article/view/574
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spelling doaj-46700f40a63848538152fd8190c5b24b2020-11-25T01:01:03Zengal-Farabi Kazakh National UniversityEurasian Chemico-Technological Journal 1562-39202522-48672004-03-0161273010.18321/ectj337574Potentiometric Control of Metal Concentration for Chelation Kinetics of Modified Polyimide FilmsJuldyz Akhmetova0Olga Moisseyevich1Andrey Kurbatov2Tleuken Akhmetov3Saule Kudaikulova4Bulat Zhubanov5Marc J.M. Abadie6Center of Physico-Chemical Analysis, al-Farabi National University 95a Vinogradov st., 480012, Almaty, KazakhstanCenter of Physico-Chemical Analysis, al-Farabi National University 95a Vinogradov st., 480012, Almaty, KazakhstanCenter of Physico-Chemical Analysis, al-Farabi National University 95a Vinogradov st., 480012, Almaty, KazakhstanCenter of Physico-Chemical Analysis, al-Farabi National University 95a Vinogradov st., 480012, Almaty, KazakhstanInstitute of Chemical Sciences, 106 Walikhanov Street, 480100, Almaty, KazakhstanInstitute of Chemical Sciences, 106 Walikhanov Street, 480100, Almaty, KazakhstanLaboratory of Polymer Science & Advance Organic Materials, Montpellier University 2 S.T.L., Place Eugène Bataillon, 34095 Montpellier Cedex 5, FranceInteraction of modified polyimide films with agrentium nitrate solutions of various concentrations was studied. Sorption of Ag ions by films is divided into three steps: formation of Ag ion layer on the border of film surface; diffusion inside the films; and final saturation of film by Ag ions. The data are confirmed by calculation of weight of the sorbed Ag ions onto the films with various thicknesses. Electrochemical Ag loading of PI films includes two parallel reactions: film dissolution accompanied by chelation.http://ect-journal.kz/index.php/ectj/article/view/574
collection DOAJ
language English
format Article
sources DOAJ
author Juldyz Akhmetova
Olga Moisseyevich
Andrey Kurbatov
Tleuken Akhmetov
Saule Kudaikulova
Bulat Zhubanov
Marc J.M. Abadie
spellingShingle Juldyz Akhmetova
Olga Moisseyevich
Andrey Kurbatov
Tleuken Akhmetov
Saule Kudaikulova
Bulat Zhubanov
Marc J.M. Abadie
Potentiometric Control of Metal Concentration for Chelation Kinetics of Modified Polyimide Films
Eurasian Chemico-Technological Journal 
author_facet Juldyz Akhmetova
Olga Moisseyevich
Andrey Kurbatov
Tleuken Akhmetov
Saule Kudaikulova
Bulat Zhubanov
Marc J.M. Abadie
author_sort Juldyz Akhmetova
title Potentiometric Control of Metal Concentration for Chelation Kinetics of Modified Polyimide Films
title_short Potentiometric Control of Metal Concentration for Chelation Kinetics of Modified Polyimide Films
title_full Potentiometric Control of Metal Concentration for Chelation Kinetics of Modified Polyimide Films
title_fullStr Potentiometric Control of Metal Concentration for Chelation Kinetics of Modified Polyimide Films
title_full_unstemmed Potentiometric Control of Metal Concentration for Chelation Kinetics of Modified Polyimide Films
title_sort potentiometric control of metal concentration for chelation kinetics of modified polyimide films
publisher al-Farabi Kazakh National University
series Eurasian Chemico-Technological Journal 
issn 1562-3920
2522-4867
publishDate 2004-03-01
description Interaction of modified polyimide films with agrentium nitrate solutions of various concentrations was studied. Sorption of Ag ions by films is divided into three steps: formation of Ag ion layer on the border of film surface; diffusion inside the films; and final saturation of film by Ag ions. The data are confirmed by calculation of weight of the sorbed Ag ions onto the films with various thicknesses. Electrochemical Ag loading of PI films includes two parallel reactions: film dissolution accompanied by chelation.
url http://ect-journal.kz/index.php/ectj/article/view/574
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