Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy

Amorphous Fe78Si9B13 ribbons and zero-valent iron (ZVI) powder were used to remove carbon tetrachloride (CTC) in the neutral oxic environment. The amorphous Fe78Si9B13 ribbons showed significantly better dechlorination performance than the ZVI powder, and the CTC could be degraded nearly completely...

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Main Authors: Changqin Zhang, Xiangyang Zhang, Shan Zhang, Hongyi Guo
Format: Article
Language:English
Published: Elsevier 2019-09-01
Series:Results in Physics
Online Access:http://www.sciencedirect.com/science/article/pii/S2211379719316377
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spelling doaj-461d585aef754401b2b7f8b7341b62172020-11-25T03:35:16ZengElsevierResults in Physics2211-37972019-09-0114Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloyChangqin Zhang0Xiangyang Zhang1Shan Zhang2Hongyi Guo3School of Materials Science and Engineering, Shandong Jianzhu University, Jinan 250101, PR China; Corresponding author.School of Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan 250101, PR ChinaSchool of Materials Science and Engineering, Shandong Jianzhu University, Jinan 250101, PR ChinaSchool of Materials Science and Engineering, Shandong Jianzhu University, Jinan 250101, PR ChinaAmorphous Fe78Si9B13 ribbons and zero-valent iron (ZVI) powder were used to remove carbon tetrachloride (CTC) in the neutral oxic environment. The amorphous Fe78Si9B13 ribbons showed significantly better dechlorination performance than the ZVI powder, and the CTC could be degraded nearly completely within 3 h. The recyclability of amorphous Fe78Si9B13 ribbons was investigated, and the results confirmed their effectiveness and stability to remove the CTC for at least ten times. Our work demonstrates the application potential of amorphous alloys as an alternative to ZVI in the dechlorination of chlorinated organic compounds, and can provide new ideas for designing efficient dechlorinating agent in the actual field groundwater remediation. Keywords: Fe-based amorphous alloys, Reductive dechlorination, Recyclability, Groundwater remediationhttp://www.sciencedirect.com/science/article/pii/S2211379719316377
collection DOAJ
language English
format Article
sources DOAJ
author Changqin Zhang
Xiangyang Zhang
Shan Zhang
Hongyi Guo
spellingShingle Changqin Zhang
Xiangyang Zhang
Shan Zhang
Hongyi Guo
Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy
Results in Physics
author_facet Changqin Zhang
Xiangyang Zhang
Shan Zhang
Hongyi Guo
author_sort Changqin Zhang
title Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy
title_short Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy
title_full Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy
title_fullStr Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy
title_full_unstemmed Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy
title_sort ultrafast reductive dechlorination of carbon tetrachloride by amorphous fe78si9b13 alloy
publisher Elsevier
series Results in Physics
issn 2211-3797
publishDate 2019-09-01
description Amorphous Fe78Si9B13 ribbons and zero-valent iron (ZVI) powder were used to remove carbon tetrachloride (CTC) in the neutral oxic environment. The amorphous Fe78Si9B13 ribbons showed significantly better dechlorination performance than the ZVI powder, and the CTC could be degraded nearly completely within 3 h. The recyclability of amorphous Fe78Si9B13 ribbons was investigated, and the results confirmed their effectiveness and stability to remove the CTC for at least ten times. Our work demonstrates the application potential of amorphous alloys as an alternative to ZVI in the dechlorination of chlorinated organic compounds, and can provide new ideas for designing efficient dechlorinating agent in the actual field groundwater remediation. Keywords: Fe-based amorphous alloys, Reductive dechlorination, Recyclability, Groundwater remediation
url http://www.sciencedirect.com/science/article/pii/S2211379719316377
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AT xiangyangzhang ultrafastreductivedechlorinationofcarbontetrachloridebyamorphousfe78si9b13alloy
AT shanzhang ultrafastreductivedechlorinationofcarbontetrachloridebyamorphousfe78si9b13alloy
AT hongyiguo ultrafastreductivedechlorinationofcarbontetrachloridebyamorphousfe78si9b13alloy
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