Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy
Amorphous Fe78Si9B13 ribbons and zero-valent iron (ZVI) powder were used to remove carbon tetrachloride (CTC) in the neutral oxic environment. The amorphous Fe78Si9B13 ribbons showed significantly better dechlorination performance than the ZVI powder, and the CTC could be degraded nearly completely...
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doaj-461d585aef754401b2b7f8b7341b62172020-11-25T03:35:16ZengElsevierResults in Physics2211-37972019-09-0114Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloyChangqin Zhang0Xiangyang Zhang1Shan Zhang2Hongyi Guo3School of Materials Science and Engineering, Shandong Jianzhu University, Jinan 250101, PR China; Corresponding author.School of Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan 250101, PR ChinaSchool of Materials Science and Engineering, Shandong Jianzhu University, Jinan 250101, PR ChinaSchool of Materials Science and Engineering, Shandong Jianzhu University, Jinan 250101, PR ChinaAmorphous Fe78Si9B13 ribbons and zero-valent iron (ZVI) powder were used to remove carbon tetrachloride (CTC) in the neutral oxic environment. The amorphous Fe78Si9B13 ribbons showed significantly better dechlorination performance than the ZVI powder, and the CTC could be degraded nearly completely within 3 h. The recyclability of amorphous Fe78Si9B13 ribbons was investigated, and the results confirmed their effectiveness and stability to remove the CTC for at least ten times. Our work demonstrates the application potential of amorphous alloys as an alternative to ZVI in the dechlorination of chlorinated organic compounds, and can provide new ideas for designing efficient dechlorinating agent in the actual field groundwater remediation. Keywords: Fe-based amorphous alloys, Reductive dechlorination, Recyclability, Groundwater remediationhttp://www.sciencedirect.com/science/article/pii/S2211379719316377 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Changqin Zhang Xiangyang Zhang Shan Zhang Hongyi Guo |
spellingShingle |
Changqin Zhang Xiangyang Zhang Shan Zhang Hongyi Guo Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy Results in Physics |
author_facet |
Changqin Zhang Xiangyang Zhang Shan Zhang Hongyi Guo |
author_sort |
Changqin Zhang |
title |
Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy |
title_short |
Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy |
title_full |
Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy |
title_fullStr |
Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy |
title_full_unstemmed |
Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy |
title_sort |
ultrafast reductive dechlorination of carbon tetrachloride by amorphous fe78si9b13 alloy |
publisher |
Elsevier |
series |
Results in Physics |
issn |
2211-3797 |
publishDate |
2019-09-01 |
description |
Amorphous Fe78Si9B13 ribbons and zero-valent iron (ZVI) powder were used to remove carbon tetrachloride (CTC) in the neutral oxic environment. The amorphous Fe78Si9B13 ribbons showed significantly better dechlorination performance than the ZVI powder, and the CTC could be degraded nearly completely within 3 h. The recyclability of amorphous Fe78Si9B13 ribbons was investigated, and the results confirmed their effectiveness and stability to remove the CTC for at least ten times. Our work demonstrates the application potential of amorphous alloys as an alternative to ZVI in the dechlorination of chlorinated organic compounds, and can provide new ideas for designing efficient dechlorinating agent in the actual field groundwater remediation. Keywords: Fe-based amorphous alloys, Reductive dechlorination, Recyclability, Groundwater remediation |
url |
http://www.sciencedirect.com/science/article/pii/S2211379719316377 |
work_keys_str_mv |
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