Radical cascades using enantioenriched 7-azabenzonorbornenes and their applications in synthesis

Tandem deoxygenation–neophyl-type radical rearrangement–electrophile trapping using xanthates from 7-azabenzonorbornadienes gives 3-exo-substituted 2-aza-5,6-benzonorbornenes, which in some cases undergo isomerisation to (aminomethyl)indenes. The starting xanthates are accessible in good yields and...

Full description

Bibliographic Details
Main Authors: David M. Hodgson, Leonard H. Winning
Format: Article
Language:English
Published: Beilstein-Institut 2008-10-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.4.38