Radical cascades using enantioenriched 7-azabenzonorbornenes and their applications in synthesis
Tandem deoxygenation–neophyl-type radical rearrangement–electrophile trapping using xanthates from 7-azabenzonorbornadienes gives 3-exo-substituted 2-aza-5,6-benzonorbornenes, which in some cases undergo isomerisation to (aminomethyl)indenes. The starting xanthates are accessible in good yields and...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
Beilstein-Institut
2008-10-01
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Series: | Beilstein Journal of Organic Chemistry |
Subjects: | |
Online Access: | https://doi.org/10.3762/bjoc.4.38 |