Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)

Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)

In the title compound, [Zn(C7H4O6S)(C19H12N4)2(H2O)], the ZnII ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO2N4 octahedral coo...

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Main Authors: Qiang Han, Xiang-Cheng Wang, Xiu-Ying Li, Guan-Xin Yao, Yong-Sheng Yan
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809039154
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spelling doaj-4607ffd91dd649f6a4b069f72f2315db2020-11-24T22:09:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1282m128310.1107/S1600536809039154Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)Qiang HanXiang-Cheng WangXiu-Ying LiGuan-Xin YaoYong-Sheng YanIn the title compound, [Zn(C7H4O6S)(C19H12N4)2(H2O)], the ZnII ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO2N4 octahedral coordination geometry for the metal ion. In the crystal, molecules are expanded into a three-dimensional supramolecular motif via O—H...O, O—H...N and N—H...(O,S) hydrogen bonds. In addition, π–π stacking interactions between the aromatic rings of the polycyclic ligands consolidate the sturcture [shortest centroid–centroid distance = 3.501 (2) Å]. http://scripts.iucr.org/cgi-bin/paper?S1600536809039154
collection DOAJ
language English
format Article
sources DOAJ
author Qiang Han
Xiang-Cheng Wang
Xiu-Ying Li
Guan-Xin Yao
Yong-Sheng Yan
spellingShingle Qiang Han
Xiang-Cheng Wang
Xiu-Ying Li
Guan-Xin Yao
Yong-Sheng Yan
Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)
Acta Crystallographica Section E
author_facet Qiang Han
Xiang-Cheng Wang
Xiu-Ying Li
Guan-Xin Yao
Yong-Sheng Yan
author_sort Qiang Han
title Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)
title_short Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)
title_full Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)
title_fullStr Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)
title_full_unstemmed Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)
title_sort aqua(2-hydroxy-5-sulfonatobenzoato-κo1)bis(2-phenyl-1h-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2n7,n8)zinc(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-11-01
description In the title compound, [Zn(C7H4O6S)(C19H12N4)2(H2O)], the ZnII ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO2N4 octahedral coordination geometry for the metal ion. In the crystal, molecules are expanded into a three-dimensional supramolecular motif via O—H...O, O—H...N and N—H...(O,S) hydrogen bonds. In addition, π–π stacking interactions between the aromatic rings of the polycyclic ligands consolidate the sturcture [shortest centroid–centroid distance = 3.501 (2) Å].
url http://scripts.iucr.org/cgi-bin/paper?S1600536809039154
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AT xiangchengwang aqua2hydroxy5sulfonatobenzoatoamp954o1bis2phenyl1h1378tetraazacyclopentalphenanthreneamp9542n7n8zincii
AT xiuyingli aqua2hydroxy5sulfonatobenzoatoamp954o1bis2phenyl1h1378tetraazacyclopentalphenanthreneamp9542n7n8zincii
AT guanxinyao aqua2hydroxy5sulfonatobenzoatoamp954o1bis2phenyl1h1378tetraazacyclopentalphenanthreneamp9542n7n8zincii
AT yongshengyan aqua2hydroxy5sulfonatobenzoatoamp954o1bis2phenyl1h1378tetraazacyclopentalphenanthreneamp9542n7n8zincii
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