| Summary: | This paper suggests a large-scale three-dimensional numerical simulation method to investigate the fluorine pollution near a slag yard. The large-scale three-dimensional numerical simulation method included an experimental investigation, laboratory studies of solute transport during absorption of water by soil, and large-scale three-dimensional numerical simulations of solute transport. The experimental results showed that the concentrations of fluorine from smelting slag and construction waste soil were well over the discharge limit of 0.1 kg/m<sup>3</sup> recommended by Chinese guidelines. The key parameters of the materials used for large-scale three-dimensional numerical simulations were determined based on an experimental investigation, laboratory studies, and soil saturation of survey results and back analyses. A large-scale three-dimensional numerical simulation of solute transport was performed, and its results were compared to the experiment results. The simulation results showed that the clay near the slag had a high saturation of approximately 0.9, consistent with the survey results. Comparison of the results showed that the results of the numerical simulation of solute transport and the test results were nearly identical, and that the numerical simulation results could be used as the basis for groundwater environmental evaluation.
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