Tetraethylammonium dibromidotricarbonyl(o-toluidine)rhenate(I)

Tetraethylammonium dibromidotricarbonyl(o-toluidine)rhenate(I)

In the title compound, (C8H20N)[ReBr2(C7H9N)(CO)3], the ReI atom is octahedrally surrounded by three carbonyl ligands orientated in a facial arrangement, two bromide ligands and an o-toluidine ligand. The amine lies trans to the carbonyl ligand and is substitutionally disordered over two positions i...

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Main Authors: Andreas Roodt, Hendrik G. Visser, Alice Brink
Format: Article
Language:English
Published: International Union of Crystallography 2011-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810050038
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spelling doaj-45dc614d7b55439d8ba002d7c55ec2632020-11-24T22:09:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-01-01671m32m3310.1107/S1600536810050038Tetraethylammonium dibromidotricarbonyl(o-toluidine)rhenate(I)Andreas RoodtHendrik G. VisserAlice BrinkIn the title compound, (C8H20N)[ReBr2(C7H9N)(CO)3], the ReI atom is octahedrally surrounded by three carbonyl ligands orientated in a facial arrangement, two bromide ligands and an o-toluidine ligand. The amine lies trans to the carbonyl ligand and is substitutionally disordered over two positions in a 0.66 (1):0.34 (1) ratio. An array of C—H...O, C—H...Br and N—H...Br hydrogen-bonding interactions between the cations and the surrounding rhenate anions stabilize the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536810050038
collection DOAJ
language English
format Article
sources DOAJ
author Andreas Roodt
Hendrik G. Visser
Alice Brink
spellingShingle Andreas Roodt
Hendrik G. Visser
Alice Brink
Tetraethylammonium dibromidotricarbonyl(o-toluidine)rhenate(I)
Acta Crystallographica Section E
author_facet Andreas Roodt
Hendrik G. Visser
Alice Brink
author_sort Andreas Roodt
title Tetraethylammonium dibromidotricarbonyl(o-toluidine)rhenate(I)
title_short Tetraethylammonium dibromidotricarbonyl(o-toluidine)rhenate(I)
title_full Tetraethylammonium dibromidotricarbonyl(o-toluidine)rhenate(I)
title_fullStr Tetraethylammonium dibromidotricarbonyl(o-toluidine)rhenate(I)
title_full_unstemmed Tetraethylammonium dibromidotricarbonyl(o-toluidine)rhenate(I)
title_sort tetraethylammonium dibromidotricarbonyl(o-toluidine)rhenate(i)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-01-01
description In the title compound, (C8H20N)[ReBr2(C7H9N)(CO)3], the ReI atom is octahedrally surrounded by three carbonyl ligands orientated in a facial arrangement, two bromide ligands and an o-toluidine ligand. The amine lies trans to the carbonyl ligand and is substitutionally disordered over two positions in a 0.66 (1):0.34 (1) ratio. An array of C—H...O, C—H...Br and N—H...Br hydrogen-bonding interactions between the cations and the surrounding rhenate anions stabilize the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810050038
work_keys_str_mv AT andreasroodt tetraethylammoniumdibromidotricarbonylotoluidinerhenatei
AT hendrikgvisser tetraethylammoniumdibromidotricarbonylotoluidinerhenatei
AT alicebrink tetraethylammoniumdibromidotricarbonylotoluidinerhenatei
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