[5-(Pyridin-2-yl)-1H-tetrazole-κ2N4,N5]bis(triphenylphosphane-κP)copper(I) tetrafluoridoborate

[5-(Pyridin-2-yl)-1H-tetrazole-κ2N4,N5]bis(triphenylphosphane-κP)copper(I) tetrafluoridoborate

In the title CuI compound, [Cu(C6H5N5)(C18H15P)2]BF4, the CuI cation is N,N′-chelated by a 5-(pyridin-2-yl)-1H-tetrazole ligand and coordinated by two triphenylphosphane ligands in a distorted tetrahedral geometry. The tetrazole and pyridine rings are essentially coplanar [dihedral ang...

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Bibliographic Details
Main Authors: Lei Lu, Ping Yang, Bing Li, Lin-Fang Shi, Hua-Ru Cao
Format: Article
Language:English
Published: International Union of Crystallography 2012-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812047605
Description
Summary:In the title CuI compound, [Cu(C6H5N5)(C18H15P)2]BF4, the CuI cation is N,N′-chelated by a 5-(pyridin-2-yl)-1H-tetrazole ligand and coordinated by two triphenylphosphane ligands in a distorted tetrahedral geometry. The tetrazole and pyridine rings are essentially coplanar [dihedral angle = 4.1 (3)°]. The tetrafluoridoborate anion links to the complex cation via an N—H...F hydrogen bond.
ISSN:1600-5368

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