Reactions of carbon radicals generated by 1,5-transposition of reactive centers

Reactions of carbon radicals generated by 1,5-transposition of reactive centers

Radical intermediates can undergo specific reactions, such as intramolecular rearrangements, i.e., the transpositions of radical centers, which are not known in classical ionic organic reactions. 1,5-Transposition of a radical center to a non-activated carbon atom are of great synthetic importance....

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Bibliographic Details
Main Author: ZIVORAD CEKOVIC
Format: Article
Language:English
Published: Serbian Chemical Society 2005-03-01
Series:Journal of the Serbian Chemical Society
Subjects:
radical reactions
1
5-transposition of radicals
hydrogen transfer
groups migration
intramolecular functionalization
Cd–C bond formation
Online Access:http://www.shd.org.yu/HtDocs/SHD/vol70/No3/JSCS_V70_No3-01.pdf

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http://www.shd.org.yu/HtDocs/SHD/vol70/No3/JSCS_V70_No3-01.pdf

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