catena-Poly[[[tetraaquanickel(II)]-μ-4,4′-bipyridyl-κ2N:N′] 3,3′-(p-phenylene)diacrylate]
In the title compound, {[Ni(C10H8N2)(H2O)4](C12H8O4)}n, the NiII, 4,4′-bipyridyl (bipy) and 3,3′-(p-phenylene)diacrylate (L2−) moieties are situated on inversion centres. The bipy ligands bridge NiII ions into positively charged polymeric chains along [101]....
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811036993 |
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doaj-44fb3417714d415a9e8fda463c99ac642020-11-25T00:35:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1397m139710.1107/S1600536811036993catena-Poly[[[tetraaquanickel(II)]-μ-4,4′-bipyridyl-κ2N:N′] 3,3′-(p-phenylene)diacrylate]Ni-Ya LiIn the title compound, {[Ni(C10H8N2)(H2O)4](C12H8O4)}n, the NiII, 4,4′-bipyridyl (bipy) and 3,3′-(p-phenylene)diacrylate (L2−) moieties are situated on inversion centres. The bipy ligands bridge NiII ions into positively charged polymeric chains along [101]. The NiII atom is coordinated by two N atoms from two bipy ligands and four water molecules in a distorted octahedral geometry. L2− anions interact with the polymeric chains via O–H...O hydrogen bonds, forming a three-dimensional supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536811036993 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Ni-Ya Li |
| spellingShingle |
Ni-Ya Li catena-Poly[[[tetraaquanickel(II)]-μ-4,4′-bipyridyl-κ2N:N′] 3,3′-(p-phenylene)diacrylate] Acta Crystallographica Section E |
| author_facet |
Ni-Ya Li |
| author_sort |
Ni-Ya Li |
| title |
catena-Poly[[[tetraaquanickel(II)]-μ-4,4′-bipyridyl-κ2N:N′] 3,3′-(p-phenylene)diacrylate] |
| title_short |
catena-Poly[[[tetraaquanickel(II)]-μ-4,4′-bipyridyl-κ2N:N′] 3,3′-(p-phenylene)diacrylate] |
| title_full |
catena-Poly[[[tetraaquanickel(II)]-μ-4,4′-bipyridyl-κ2N:N′] 3,3′-(p-phenylene)diacrylate] |
| title_fullStr |
catena-Poly[[[tetraaquanickel(II)]-μ-4,4′-bipyridyl-κ2N:N′] 3,3′-(p-phenylene)diacrylate] |
| title_full_unstemmed |
catena-Poly[[[tetraaquanickel(II)]-μ-4,4′-bipyridyl-κ2N:N′] 3,3′-(p-phenylene)diacrylate] |
| title_sort |
catena-poly[[[tetraaquanickel(ii)]-μ-4,4′-bipyridyl-κ2n:n′] 3,3′-(p-phenylene)diacrylate] |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-10-01 |
| description |
In the title compound, {[Ni(C10H8N2)(H2O)4](C12H8O4)}n, the NiII, 4,4′-bipyridyl (bipy) and 3,3′-(p-phenylene)diacrylate (L2−) moieties are situated on inversion centres. The bipy ligands bridge NiII ions into positively charged polymeric chains along [101]. The NiII atom is coordinated by two N atoms from two bipy ligands and four water molecules in a distorted octahedral geometry. L2− anions interact with the polymeric chains via O–H...O hydrogen bonds, forming a three-dimensional supramolecular network. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811036993 |
| work_keys_str_mv |
AT niyali catenapolytetraaquanickeliiamp95644amp8242bipyridylamp9542nnamp824233amp8242pphenylenediacrylate |
| _version_ |
1725307003722530816 |