Vibronic coherence evolution in multidimensional ultrafast photochemical processes

Energy transfer in light harvesting complexes involves electronic, vibrational, and vibronic couplings which are challenging to resolve. Here the authors observe the time-evolution of vibronic coherences driving charge transfer in a photoexcited solvated transition metal complex by two- and three-di...

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Main Authors: James D. Gaynor, Jason Sandwisch, Munira Khalil
Format: Article
Language:English
Published: Nature Publishing Group 2019-12-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-13503-9
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spelling doaj-44f0bc61b83e4eeb9d596961142a6fc62021-01-31T15:37:40ZengNature Publishing GroupNature Communications2041-17232019-12-011011910.1038/s41467-019-13503-9Vibronic coherence evolution in multidimensional ultrafast photochemical processesJames D. Gaynor0Jason Sandwisch1Munira Khalil2Department of Chemistry, University of WashingtonDepartment of Chemistry, University of WashingtonDepartment of Chemistry, University of WashingtonEnergy transfer in light harvesting complexes involves electronic, vibrational, and vibronic couplings which are challenging to resolve. Here the authors observe the time-evolution of vibronic coherences driving charge transfer in a photoexcited solvated transition metal complex by two- and three-dimensional electronic-vibrational spectroscopy.https://doi.org/10.1038/s41467-019-13503-9
collection DOAJ
language English
format Article
sources DOAJ
author James D. Gaynor
Jason Sandwisch
Munira Khalil
spellingShingle James D. Gaynor
Jason Sandwisch
Munira Khalil
Vibronic coherence evolution in multidimensional ultrafast photochemical processes
Nature Communications
author_facet James D. Gaynor
Jason Sandwisch
Munira Khalil
author_sort James D. Gaynor
title Vibronic coherence evolution in multidimensional ultrafast photochemical processes
title_short Vibronic coherence evolution in multidimensional ultrafast photochemical processes
title_full Vibronic coherence evolution in multidimensional ultrafast photochemical processes
title_fullStr Vibronic coherence evolution in multidimensional ultrafast photochemical processes
title_full_unstemmed Vibronic coherence evolution in multidimensional ultrafast photochemical processes
title_sort vibronic coherence evolution in multidimensional ultrafast photochemical processes
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2019-12-01
description Energy transfer in light harvesting complexes involves electronic, vibrational, and vibronic couplings which are challenging to resolve. Here the authors observe the time-evolution of vibronic coherences driving charge transfer in a photoexcited solvated transition metal complex by two- and three-dimensional electronic-vibrational spectroscopy.
url https://doi.org/10.1038/s41467-019-13503-9
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AT jasonsandwisch vibroniccoherenceevolutioninmultidimensionalultrafastphotochemicalprocesses
AT munirakhalil vibroniccoherenceevolutioninmultidimensionalultrafastphotochemicalprocesses
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