Vibronic coherence evolution in multidimensional ultrafast photochemical processes
Energy transfer in light harvesting complexes involves electronic, vibrational, and vibronic couplings which are challenging to resolve. Here the authors observe the time-evolution of vibronic coherences driving charge transfer in a photoexcited solvated transition metal complex by two- and three-di...
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2019-12-01
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Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-019-13503-9 |
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doaj-44f0bc61b83e4eeb9d596961142a6fc62021-01-31T15:37:40ZengNature Publishing GroupNature Communications2041-17232019-12-011011910.1038/s41467-019-13503-9Vibronic coherence evolution in multidimensional ultrafast photochemical processesJames D. Gaynor0Jason Sandwisch1Munira Khalil2Department of Chemistry, University of WashingtonDepartment of Chemistry, University of WashingtonDepartment of Chemistry, University of WashingtonEnergy transfer in light harvesting complexes involves electronic, vibrational, and vibronic couplings which are challenging to resolve. Here the authors observe the time-evolution of vibronic coherences driving charge transfer in a photoexcited solvated transition metal complex by two- and three-dimensional electronic-vibrational spectroscopy.https://doi.org/10.1038/s41467-019-13503-9 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
James D. Gaynor Jason Sandwisch Munira Khalil |
spellingShingle |
James D. Gaynor Jason Sandwisch Munira Khalil Vibronic coherence evolution in multidimensional ultrafast photochemical processes Nature Communications |
author_facet |
James D. Gaynor Jason Sandwisch Munira Khalil |
author_sort |
James D. Gaynor |
title |
Vibronic coherence evolution in multidimensional ultrafast photochemical processes |
title_short |
Vibronic coherence evolution in multidimensional ultrafast photochemical processes |
title_full |
Vibronic coherence evolution in multidimensional ultrafast photochemical processes |
title_fullStr |
Vibronic coherence evolution in multidimensional ultrafast photochemical processes |
title_full_unstemmed |
Vibronic coherence evolution in multidimensional ultrafast photochemical processes |
title_sort |
vibronic coherence evolution in multidimensional ultrafast photochemical processes |
publisher |
Nature Publishing Group |
series |
Nature Communications |
issn |
2041-1723 |
publishDate |
2019-12-01 |
description |
Energy transfer in light harvesting complexes involves electronic, vibrational, and vibronic couplings which are challenging to resolve. Here the authors observe the time-evolution of vibronic coherences driving charge transfer in a photoexcited solvated transition metal complex by two- and three-dimensional electronic-vibrational spectroscopy. |
url |
https://doi.org/10.1038/s41467-019-13503-9 |
work_keys_str_mv |
AT jamesdgaynor vibroniccoherenceevolutioninmultidimensionalultrafastphotochemicalprocesses AT jasonsandwisch vibroniccoherenceevolutioninmultidimensionalultrafastphotochemicalprocesses AT munirakhalil vibroniccoherenceevolutioninmultidimensionalultrafastphotochemicalprocesses |
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1724316935812808704 |