Phase diagrams for the M2MoO4–Ln2(MoO4)3–Hf(MoO4)2 systems, where M = Li–Cs, Tl and Ln = La–Lu

Phase diagrams for the M2MoO4–Ln2(MoO4)3–Hf(MoO4)2 systems, where M = Li–Cs, Tl and Ln = La–Lu

In this paper, the results of systematic studies of complex molybdate systems M2MoO4–Ln2(MoO4)3–Hf(MoO4)2 (M = Li–Cs, Tl; Ln = La–Lu) are presented. Subsolidus phase diagrams of ternary systems were constructed and new triple molybdates were obtained. The optimum synthesis conditions for poly- and m...

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Bibliographic Details
Main Authors: Zh. G. Bazarova, V. G. Grossman, B. G. Bazarov, Yu. L. Tushinova, O. D. Chimitova, Ts. T. Bazarova
Format: Article
Language:English
Published: Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina 2017-12-01
Series:Chimica Techno Acta
Subjects:
phase equilibria
synthesis
systems
lithium
sodium
potassium
rubidium, cesium
thallium
lanthanides
hafnium
crystal structure
Online Access:https://journals.urfu.ru/index.php/chimtech/article/view/2717
Description
Summary:In this paper, the results of systematic studies of complex molybdate systems M2MoO4–Ln2(MoO4)3–Hf(MoO4)2 (M = Li–Cs, Tl; Ln = La–Lu) are presented. Subsolidus phase diagrams of ternary systems were constructed and new triple molybdates were obtained. The optimum synthesis conditions for poly- and monocrystalline form were determined. According to single-crystal data, the structure of one of the representatives of triple molybdates was determined.
ISSN:2409-5613
2411-1414

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