Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine

Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine

A new Cd(II) complex with the ligand 4′-chloro-2,2′6′,2′′-terpyridine (Cltpy), [Cd(Cltpy)(I)2], has been synthesized and characterized by CHN elemental analysis, 1H-NMR, 13C-NMR, and IR spectroscopy and structurally analyzed by X-ray single-crystal diffraction. The single-crystal X-ray analyses sho...

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Main Authors: L. A. Saghatforoush, L. Valencia, F. Chalabian, Sh. Ghammamy
Format: Article
Language:English
Published: Hindawi Limited 2011-01-01
Series:Bioinorganic Chemistry and Applications
Online Access:http://dx.doi.org/10.1155/2011/803292
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spelling doaj-448b615249214c00bb58d27991ad650b2020-11-25T02:16:48ZengHindawi LimitedBioinorganic Chemistry and Applications1565-36331687-479X2011-01-01201110.1155/2011/803292803292Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-TerpyridineL. A. Saghatforoush0L. Valencia1F. Chalabian2Sh. Ghammamy3Chemistry Department, Payame Noor University, Tehran 19395-4697, IranDepartamento de Quimica Inorganica, Facultad de Quimica, Universidade de Vigo, 36310 Vigo, SpainDepartment of Biology, Islamic Azad University, Tehran North Campus, Tehran, IranDepartment of Chemistry, Imam Khomeini International University, Qazvin 34149-16818, IranA new Cd(II) complex with the ligand 4′-chloro-2,2′6′,2′′-terpyridine (Cltpy), [Cd(Cltpy)(I)2], has been synthesized and characterized by CHN elemental analysis, 1H-NMR, 13C-NMR, and IR spectroscopy and structurally analyzed by X-ray single-crystal diffraction. The single-crystal X-ray analyses show that the coordination number in complex is five with three terpyridine (Cltpy) N-donor atoms and two iodine atoms. The antibacterial activities of Cltpy and its Cd(II) complex are tested against different bacteria.http://dx.doi.org/10.1155/2011/803292
collection DOAJ
language English
format Article
sources DOAJ
author L. A. Saghatforoush
L. Valencia
F. Chalabian
Sh. Ghammamy
spellingShingle L. A. Saghatforoush
L. Valencia
F. Chalabian
Sh. Ghammamy
Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine
Bioinorganic Chemistry and Applications
author_facet L. A. Saghatforoush
L. Valencia
F. Chalabian
Sh. Ghammamy
author_sort L. A. Saghatforoush
title Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine
title_short Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine
title_full Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine
title_fullStr Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine
title_full_unstemmed Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine
title_sort synthesis, characterization, crystal structure, and biological studies of a cadmium(ii) complex with a tridentate ligand 4′-chloro-2,2′:6′,2′′-terpyridine
publisher Hindawi Limited
series Bioinorganic Chemistry and Applications
issn 1565-3633
1687-479X
publishDate 2011-01-01
description A new Cd(II) complex with the ligand 4′-chloro-2,2′6′,2′′-terpyridine (Cltpy), [Cd(Cltpy)(I)2], has been synthesized and characterized by CHN elemental analysis, 1H-NMR, 13C-NMR, and IR spectroscopy and structurally analyzed by X-ray single-crystal diffraction. The single-crystal X-ray analyses show that the coordination number in complex is five with three terpyridine (Cltpy) N-donor atoms and two iodine atoms. The antibacterial activities of Cltpy and its Cd(II) complex are tested against different bacteria.
url http://dx.doi.org/10.1155/2011/803292
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