Interesting Behavior of Pachycormus discolor Leaves Ethanol Extract as a Corrosion Inhibitor of Carbon Steel in 1 M HCl: A Preliminary Study

The purpose of this paper is to evaluate the inhibitive action of an ethanol extract from the leaves of Pachycormus discolor (EEPD) on the corrosion of carbon steel in 1 M HCl at different temperatures; gravimetric method and electrochemical tests were conducted. Potentiodynamic polarization was use...

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Main Authors: Ramses Garcia Inzunza, Benjamín Valdez Salas, Rita Kharshan, Alla Furman, Michael Schorr Wienner
Format: Article
Language:English
Published: Hindawi Limited 2012-01-01
Series:International Journal of Corrosion
Online Access:http://dx.doi.org/10.1155/2012/980654
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spelling doaj-443cbb4a67364f139d1b0d9699be01102020-11-24T23:49:36ZengHindawi LimitedInternational Journal of Corrosion1687-93251687-93332012-01-01201210.1155/2012/980654980654Interesting Behavior of Pachycormus discolor Leaves Ethanol Extract as a Corrosion Inhibitor of Carbon Steel in 1 M HCl: A Preliminary StudyRamses Garcia Inzunza0Benjamín Valdez Salas1Rita Kharshan2Alla Furman3Michael Schorr Wienner4Laboratory of Corrosion and Material, Institute of Engineering, Autonomous University of Baja California, Blvd. Benito Juárez y Calle de la Normal, S/N, 21280 Mexicali, BC, MexicoLaboratory of Corrosion and Material, Institute of Engineering, Autonomous University of Baja California, Blvd. Benito Juárez y Calle de la Normal, S/N, 21280 Mexicali, BC, MexicoCortec Corporation, 4119 White Bear Parkway, St. Paul, MN 55110, USACortec Corporation, 4119 White Bear Parkway, St. Paul, MN 55110, USALaboratory of Corrosion and Material, Institute of Engineering, Autonomous University of Baja California, Blvd. Benito Juárez y Calle de la Normal, S/N, 21280 Mexicali, BC, MexicoThe purpose of this paper is to evaluate the inhibitive action of an ethanol extract from the leaves of Pachycormus discolor (EEPD) on the corrosion of carbon steel in 1 M HCl at different temperatures; gravimetric method and electrochemical tests were conducted. Potentiodynamic polarization was used at room temperature and resistance polarization at different temperatures. Thermodynamic adsorption parameters are shown in order to demonstrate the spontaneous adsorption. The inhibition of EEPD was performed via adsorption of the extract species on the carbon steel surface. The ethanol extract obeys Langmuir adsorption isotherm. Potentiodynamic polarization results indicate that the ethanol extract acts as a mixed type inhibitor. The results revealed that the inhibition efficiency (IE) of EEPD increases (when the concentration is increased). Phytochemical and FTIR analyses are also presented in this work. It was found that the IE increases with the temperature in a 2.0% v/v solution which showed 94.52% IE at 25∘C and 97.89% at 75∘C.http://dx.doi.org/10.1155/2012/980654
collection DOAJ
language English
format Article
sources DOAJ
author Ramses Garcia Inzunza
Benjamín Valdez Salas
Rita Kharshan
Alla Furman
Michael Schorr Wienner
spellingShingle Ramses Garcia Inzunza
Benjamín Valdez Salas
Rita Kharshan
Alla Furman
Michael Schorr Wienner
Interesting Behavior of Pachycormus discolor Leaves Ethanol Extract as a Corrosion Inhibitor of Carbon Steel in 1 M HCl: A Preliminary Study
International Journal of Corrosion
author_facet Ramses Garcia Inzunza
Benjamín Valdez Salas
Rita Kharshan
Alla Furman
Michael Schorr Wienner
author_sort Ramses Garcia Inzunza
title Interesting Behavior of Pachycormus discolor Leaves Ethanol Extract as a Corrosion Inhibitor of Carbon Steel in 1 M HCl: A Preliminary Study
title_short Interesting Behavior of Pachycormus discolor Leaves Ethanol Extract as a Corrosion Inhibitor of Carbon Steel in 1 M HCl: A Preliminary Study
title_full Interesting Behavior of Pachycormus discolor Leaves Ethanol Extract as a Corrosion Inhibitor of Carbon Steel in 1 M HCl: A Preliminary Study
title_fullStr Interesting Behavior of Pachycormus discolor Leaves Ethanol Extract as a Corrosion Inhibitor of Carbon Steel in 1 M HCl: A Preliminary Study
title_full_unstemmed Interesting Behavior of Pachycormus discolor Leaves Ethanol Extract as a Corrosion Inhibitor of Carbon Steel in 1 M HCl: A Preliminary Study
title_sort interesting behavior of pachycormus discolor leaves ethanol extract as a corrosion inhibitor of carbon steel in 1 m hcl: a preliminary study
publisher Hindawi Limited
series International Journal of Corrosion
issn 1687-9325
1687-9333
publishDate 2012-01-01
description The purpose of this paper is to evaluate the inhibitive action of an ethanol extract from the leaves of Pachycormus discolor (EEPD) on the corrosion of carbon steel in 1 M HCl at different temperatures; gravimetric method and electrochemical tests were conducted. Potentiodynamic polarization was used at room temperature and resistance polarization at different temperatures. Thermodynamic adsorption parameters are shown in order to demonstrate the spontaneous adsorption. The inhibition of EEPD was performed via adsorption of the extract species on the carbon steel surface. The ethanol extract obeys Langmuir adsorption isotherm. Potentiodynamic polarization results indicate that the ethanol extract acts as a mixed type inhibitor. The results revealed that the inhibition efficiency (IE) of EEPD increases (when the concentration is increased). Phytochemical and FTIR analyses are also presented in this work. It was found that the IE increases with the temperature in a 2.0% v/v solution which showed 94.52% IE at 25∘C and 97.89% at 75∘C.
url http://dx.doi.org/10.1155/2012/980654
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