Synthesis and Structures of Ruthenium Carbonyl Complexes Bearing Pyridine-Alkoxide Ligands and Their Catalytic Activity in Alcohol Oxidation

Synthesis and Structures of Ruthenium Carbonyl Complexes Bearing Pyridine-Alkoxide Ligands and Their Catalytic Activity in Alcohol Oxidation

Reaction of Ru3(CO)12 with two equiv of 6-bromopyridine alcohols 6-bromopyCHROH [(R = C6H5 (L1); R = 4-CH3C6H4 (L2); R = 4-OMeC6H4 (L3); R = 4-ClC6H4 (L4); (R = 4-CF3C6H4 (L5); R = 2-OMeC6H4 (L6); R = 2-CF3C6H4 (L7)] and 6-bromopyC(Me)2OH (L8) in refluxing xylene afforded novel trinuclear ruthenium...

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Bibliographic Details
Main Authors: Xinlong Yan, Xiaohui Yue, Kang Liu, Zhiqiang Hao, Zhangang Han, Jin Lin
Format: Article
Language:English
Published: Frontiers Media S.A. 2019-06-01
Series:Frontiers in Chemistry
Subjects:
ruthenium carbonyl complexes
alcohols oxidation
t-butyl hydroperoxide
pyridine alcohols
chemoselectivity
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2019.00394/full

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