Electronic Effects of Substituents on fac-M(bpy-R)(CO)3 (M = Mn, Re) Complexes for Homogeneous CO2 Electroreduction

Electronic Effects of Substituents on fac-M(bpy-R)(CO)3 (M = Mn, Re) Complexes for Homogeneous CO2 Electroreduction

Synthesis and characterization of 14 new 2,2′-bipyridine metal complexes fac-M(bpy-R)(CO)3X (where M = Mn, X = Br or M = Re, X = Cl and R = -CF3, -CN, -Ph, -PhOH, -NMe2) are reported. The complexes have been characterized by NMR, IR spectroscopy and elemental analysis. Single crystal X-Ray diffracti...

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Bibliographic Details
Main Authors: Laura Rotundo, Emanuele Azzi, Annamaria Deagostino, Claudio Garino, Luca Nencini, Emanuele Priola, Pierluigi Quagliotto, Riccardo Rocca, Roberto Gobetto, Carlo Nervi
Format: Article
Language:English
Published: Frontiers Media S.A. 2019-06-01
Series:Frontiers in Chemistry
Subjects:
CO2 electroreduction
Mn complexes
Re complexes
DFT calculations
bipy ligands
homogeneous catalysis
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2019.00417/full

Internet

https://www.frontiersin.org/article/10.3389/fchem.2019.00417/full

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