2-{1-[2-((2-Ammonioethyl){2-[1-(5-chloro-2-hydroxyphenyl)ethylideneamino]ethyl}amino)ethyliminio]ethyl}-4-chlorophenolate trifluoroacetate

In the title ion-pair, C22H29Cl2N4O2+·C2F3O2−, ammonium–carboxylate N—H...O hydrogen bonds link two cations and two anions about a centre of inversion to generate a hydrogen-bonded tetramer. In the cation, one of the imino N atoms is protonated and donates a hy...

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Main Authors: Seik Weng Ng, Kong Mun Lo, Hapipah Mohd. Ali, See Mun Lee
Format: Article
Language:English
Published: International Union of Crystallography 2009-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809002943
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spelling doaj-43805c9d171e4b7598959c6f6b7959b82020-11-24T21:32:21ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652o410o41010.1107/S16005368090029432-{1-[2-((2-Ammonioethyl){2-[1-(5-chloro-2-hydroxyphenyl)ethylideneamino]ethyl}amino)ethyliminio]ethyl}-4-chlorophenolate trifluoroacetateSeik Weng NgKong Mun LoHapipah Mohd. AliSee Mun LeeIn the title ion-pair, C22H29Cl2N4O2+·C2F3O2−, ammonium–carboxylate N—H...O hydrogen bonds link two cations and two anions about a centre of inversion to generate a hydrogen-bonded tetramer. In the cation, one of the imino N atoms is protonated and donates a hydrogen bond to the O atom of the adjacent chlorophenyl ring. The other imino N atom acts as a hydrogen-bond acceptor from a phenolate O atom.http://scripts.iucr.org/cgi-bin/paper?S1600536809002943
collection DOAJ
language English
format Article
sources DOAJ
author Seik Weng Ng
Kong Mun Lo
Hapipah Mohd. Ali
See Mun Lee
spellingShingle Seik Weng Ng
Kong Mun Lo
Hapipah Mohd. Ali
See Mun Lee
2-{1-[2-((2-Ammonioethyl){2-[1-(5-chloro-2-hydroxyphenyl)ethylideneamino]ethyl}amino)ethyliminio]ethyl}-4-chlorophenolate trifluoroacetate
Acta Crystallographica Section E
author_facet Seik Weng Ng
Kong Mun Lo
Hapipah Mohd. Ali
See Mun Lee
author_sort Seik Weng Ng
title 2-{1-[2-((2-Ammonioethyl){2-[1-(5-chloro-2-hydroxyphenyl)ethylideneamino]ethyl}amino)ethyliminio]ethyl}-4-chlorophenolate trifluoroacetate
title_short 2-{1-[2-((2-Ammonioethyl){2-[1-(5-chloro-2-hydroxyphenyl)ethylideneamino]ethyl}amino)ethyliminio]ethyl}-4-chlorophenolate trifluoroacetate
title_full 2-{1-[2-((2-Ammonioethyl){2-[1-(5-chloro-2-hydroxyphenyl)ethylideneamino]ethyl}amino)ethyliminio]ethyl}-4-chlorophenolate trifluoroacetate
title_fullStr 2-{1-[2-((2-Ammonioethyl){2-[1-(5-chloro-2-hydroxyphenyl)ethylideneamino]ethyl}amino)ethyliminio]ethyl}-4-chlorophenolate trifluoroacetate
title_full_unstemmed 2-{1-[2-((2-Ammonioethyl){2-[1-(5-chloro-2-hydroxyphenyl)ethylideneamino]ethyl}amino)ethyliminio]ethyl}-4-chlorophenolate trifluoroacetate
title_sort 2-{1-[2-((2-ammonioethyl){2-[1-(5-chloro-2-hydroxyphenyl)ethylideneamino]ethyl}amino)ethyliminio]ethyl}-4-chlorophenolate trifluoroacetate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-02-01
description In the title ion-pair, C22H29Cl2N4O2+·C2F3O2−, ammonium–carboxylate N—H...O hydrogen bonds link two cations and two anions about a centre of inversion to generate a hydrogen-bonded tetramer. In the cation, one of the imino N atoms is protonated and donates a hydrogen bond to the O atom of the adjacent chlorophenyl ring. The other imino N atom acts as a hydrogen-bond acceptor from a phenolate O atom.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809002943
work_keys_str_mv AT seikwengng 2122ammonioethyl215chloro2hydroxyphenylethylideneaminoethylaminoethyliminioethyl4chlorophenolatetrifluoroacetate
AT kongmunlo 2122ammonioethyl215chloro2hydroxyphenylethylideneaminoethylaminoethyliminioethyl4chlorophenolatetrifluoroacetate
AT hapipahmohdali 2122ammonioethyl215chloro2hydroxyphenylethylideneaminoethylaminoethyliminioethyl4chlorophenolatetrifluoroacetate
AT seemunlee 2122ammonioethyl215chloro2hydroxyphenylethylideneaminoethylaminoethyliminioethyl4chlorophenolatetrifluoroacetate
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