trans-Bis(4-methoxythiophenolato-κS)bis(trimethylphosphine-κP)nickel(II)

trans-Bis(4-methoxythiophenolato-κS)bis(trimethylphosphine-κP)nickel(II)

The title compound, [Ni(C7H7OS)2(C3H9P)2], was obtained as a product of the reaction of [NiMe2(PMe3)3] with two molar equivalents of 4-methoxythiophenol in diethyl ether. The compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The Ni atom displays...

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Main Authors: Hongjian Sun, Qibao Wang, Ruixia Cao
Format: Article
Language:English
Published: International Union of Crystallography 2008-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807067591
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spelling doaj-4349582ab39f4f0a85c9bdcec9aa60ca2020-11-24T21:53:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m279m27910.1107/S1600536807067591trans-Bis(4-methoxythiophenolato-κS)bis(trimethylphosphine-κP)nickel(II)Hongjian SunQibao WangRuixia CaoThe title compound, [Ni(C7H7OS)2(C3H9P)2], was obtained as a product of the reaction of [NiMe2(PMe3)3] with two molar equivalents of 4-methoxythiophenol in diethyl ether. The compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The Ni atom displays a square-planar coordination with two P-donor atoms lying in trans positions. The benzene rings of the thiophenolate ligands are almost perpendicular to the square coordination plane, making dihedral angles of 80.43 (4) and 72.60 (4)°.http://scripts.iucr.org/cgi-bin/paper?S1600536807067591
collection DOAJ
language English
format Article
sources DOAJ
author Hongjian Sun
Qibao Wang
Ruixia Cao
spellingShingle Hongjian Sun
Qibao Wang
Ruixia Cao
trans-Bis(4-methoxythiophenolato-κS)bis(trimethylphosphine-κP)nickel(II)
Acta Crystallographica Section E
author_facet Hongjian Sun
Qibao Wang
Ruixia Cao
author_sort Hongjian Sun
title trans-Bis(4-methoxythiophenolato-κS)bis(trimethylphosphine-κP)nickel(II)
title_short trans-Bis(4-methoxythiophenolato-κS)bis(trimethylphosphine-κP)nickel(II)
title_full trans-Bis(4-methoxythiophenolato-κS)bis(trimethylphosphine-κP)nickel(II)
title_fullStr trans-Bis(4-methoxythiophenolato-κS)bis(trimethylphosphine-κP)nickel(II)
title_full_unstemmed trans-Bis(4-methoxythiophenolato-κS)bis(trimethylphosphine-κP)nickel(II)
title_sort trans-bis(4-methoxythiophenolato-κs)bis(trimethylphosphine-κp)nickel(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-02-01
description The title compound, [Ni(C7H7OS)2(C3H9P)2], was obtained as a product of the reaction of [NiMe2(PMe3)3] with two molar equivalents of 4-methoxythiophenol in diethyl ether. The compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The Ni atom displays a square-planar coordination with two P-donor atoms lying in trans positions. The benzene rings of the thiophenolate ligands are almost perpendicular to the square coordination plane, making dihedral angles of 80.43 (4) and 72.60 (4)°.
url http://scripts.iucr.org/cgi-bin/paper?S1600536807067591
work_keys_str_mv AT hongjiansun transbis4methoxythiophenolato954sbistrimethylphosphine954pnickelii
AT qibaowang transbis4methoxythiophenolato954sbistrimethylphosphine954pnickelii
AT ruixiacao transbis4methoxythiophenolato954sbistrimethylphosphine954pnickelii
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