Crystal structure of fenpropathrin

Crystal structure of fenpropathrin

In the title compound [systematic name: cyano(3-phenoxyphenyl)methyl 2,2,3,3-tetramethylcyclopropanecarboxylate], C22H23NO3, which is the pyrethroid insecticide fenpropathrin, the dihedral angle between the cyclopropane ring plane and the carboxylate group plane is 88.25 (11)°. The dihedral angle be...

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Main Authors: Gihaeng Kang, Youngeun Jeon, Sangjin Lee, Tae Ho Kim
Format: Article
Language:English
Published: International Union of Crystallography 2014-12-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
fenpropathrin
cyclopropanecarboxylate
pyrethroid insecticide
C—H...π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681402474X
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spelling doaj-431df4bd98cf4ba99f84d30bd4f799352020-11-24T21:48:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-12-017012o1265o126510.1107/S160053681402474Xhg5417Crystal structure of fenpropathrinGihaeng Kang0Youngeun Jeon1Sangjin Lee2Tae Ho Kim3Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 660-701, Republic of KoreaDepartment of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 660-701, Republic of KoreaDepartment of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 660-701, Republic of KoreaDepartment of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 660-701, Republic of KoreaIn the title compound [systematic name: cyano(3-phenoxyphenyl)methyl 2,2,3,3-tetramethylcyclopropanecarboxylate], C22H23NO3, which is the pyrethroid insecticide fenpropathrin, the dihedral angle between the cyclopropane ring plane and the carboxylate group plane is 88.25 (11)°. The dihedral angle between the benzene and phenyl rings in the phenoxybenzyl group is 82.99 (4)°. In the crystal, C—H...N hydrogen bonds and weak C—H...π interactions link adjacent molecules, forming loop chains along the b-axis direction.http://scripts.iucr.org/cgi-bin/paper?S160053681402474Xcrystal structurefenpropathrincyclopropanecarboxylatepyrethroid insecticideC—H...π interactions
collection DOAJ
language English
format Article
sources DOAJ
author Gihaeng Kang
Youngeun Jeon
Sangjin Lee
Tae Ho Kim
spellingShingle Gihaeng Kang
Youngeun Jeon
Sangjin Lee
Tae Ho Kim
Crystal structure of fenpropathrin
Acta Crystallographica Section E
crystal structure
fenpropathrin
cyclopropanecarboxylate
pyrethroid insecticide
C—H...π interactions
author_facet Gihaeng Kang
Youngeun Jeon
Sangjin Lee
Tae Ho Kim
author_sort Gihaeng Kang
title Crystal structure of fenpropathrin
title_short Crystal structure of fenpropathrin
title_full Crystal structure of fenpropathrin
title_fullStr Crystal structure of fenpropathrin
title_full_unstemmed Crystal structure of fenpropathrin
title_sort crystal structure of fenpropathrin
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-12-01
description In the title compound [systematic name: cyano(3-phenoxyphenyl)methyl 2,2,3,3-tetramethylcyclopropanecarboxylate], C22H23NO3, which is the pyrethroid insecticide fenpropathrin, the dihedral angle between the cyclopropane ring plane and the carboxylate group plane is 88.25 (11)°. The dihedral angle between the benzene and phenyl rings in the phenoxybenzyl group is 82.99 (4)°. In the crystal, C—H...N hydrogen bonds and weak C—H...π interactions link adjacent molecules, forming loop chains along the b-axis direction.
topic crystal structure
fenpropathrin
cyclopropanecarboxylate
pyrethroid insecticide
C—H...π interactions
url http://scripts.iucr.org/cgi-bin/paper?S160053681402474X
work_keys_str_mv AT gihaengkang crystalstructureoffenpropathrin
AT youngeunjeon crystalstructureoffenpropathrin
AT sangjinlee crystalstructureoffenpropathrin
AT taehokim crystalstructureoffenpropathrin
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