Acetylferrocene–2-chloro-1-ferrocenylethanone (1/1)

Acetylferrocene–2-chloro-1-ferrocenylethanone (1/1)

In the title co-crystal, [Fe(C5H5)(C7H6ClO)][Fe(C5H5)(C7H7O)], both substituted ferrocene molecules show the expected sandwich structure. The crystal packing exhibits weak intermolecular Cl...Cl contacts of 3.279 (4) Å, π–&#...

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Main Authors: Aleš Růžička, Jaromír Vinklárek, Milan Erben
Format: Article
Language:English
Published: International Union of Crystallography 2011-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811038244
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spelling doaj-42f1dc35359443829274141d58452e492020-11-25T01:17:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1447m144810.1107/S1600536811038244Acetylferrocene–2-chloro-1-ferrocenylethanone (1/1)Aleš RůžičkaJaromír VinklárekMilan ErbenIn the title co-crystal, [Fe(C5H5)(C7H6ClO)][Fe(C5H5)(C7H7O)], both substituted ferrocene molecules show the expected sandwich structure. The crystal packing exhibits weak intermolecular Cl...Cl contacts of 3.279 (4) Å, π–π interactions between the substituted Cp rings of two neighbouring 2-chloro-1-ferrocenylethanone molecules [centroid–centroid distance = 3.534 (3) Å], and weak intermolecular C—H...O and C—H...Cl hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536811038244
collection DOAJ
language English
format Article
sources DOAJ
author Aleš Růžička
Jaromír Vinklárek
Milan Erben
spellingShingle Aleš Růžička
Jaromír Vinklárek
Milan Erben
Acetylferrocene–2-chloro-1-ferrocenylethanone (1/1)
Acta Crystallographica Section E
author_facet Aleš Růžička
Jaromír Vinklárek
Milan Erben
author_sort Aleš Růžička
title Acetylferrocene–2-chloro-1-ferrocenylethanone (1/1)
title_short Acetylferrocene–2-chloro-1-ferrocenylethanone (1/1)
title_full Acetylferrocene–2-chloro-1-ferrocenylethanone (1/1)
title_fullStr Acetylferrocene–2-chloro-1-ferrocenylethanone (1/1)
title_full_unstemmed Acetylferrocene–2-chloro-1-ferrocenylethanone (1/1)
title_sort acetylferrocene–2-chloro-1-ferrocenylethanone (1/1)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-10-01
description In the title co-crystal, [Fe(C5H5)(C7H6ClO)][Fe(C5H5)(C7H7O)], both substituted ferrocene molecules show the expected sandwich structure. The crystal packing exhibits weak intermolecular Cl...Cl contacts of 3.279 (4) Å, π–π interactions between the substituted Cp rings of two neighbouring 2-chloro-1-ferrocenylethanone molecules [centroid–centroid distance = 3.534 (3) Å], and weak intermolecular C—H...O and C—H...Cl hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811038244
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AT jaromamp237rvinklamp225rek acetylferroceneamp82112chloro1ferrocenylethanone11
AT milanerben acetylferroceneamp82112chloro1ferrocenylethanone11
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