2-(3-Benzoyl-4-hydroxy-1,1-dioxo-2H-1λ6,2-benzothiazin-2-yl)-1-phenylethanone

• Main Authors: Nazia Sattar, Hamid Latif Siddiqui, Syed Iftikhar Hussain Bukhari, Matloob Ahmad, Masood Parvez
• Format: Article
• Language: English
• Published: International Union of Crystallography 2012-01-01
• Series: Acta Crystallographica Section E
• Online Access: http://scripts.iucr.org/cgi-bin/paper?S1600536811052615

In the title molecule, C23H17NO5S, the heterocyclic thiazine ring adopts a half-chair conformation, with the S and N atoms displaced by 0.383 (3) and 0.473 (3) Å, respectively, on opposite sides of the mean plane formed by the ring C atoms. The phenyl rings attached to carbonyl groups lie almost parallel to each other at a dihedral angle 7.43 (9)°, the distance between the centroids of the rings being 3.780 (1) Å. The C(thiazine)—C=O and O=C—CH2 groups make dihedral angles of 37.56 (16) and 1.93 (18)°, respectively, with the phenyl groups to which they are attached. The crystal structure features O—H...O and C—H...O hydrogen bonds and further consolidated by C—H...π interactions; an intramolecular O—H...O hydrogen bond is also present.