2-[(2Z)-Azepan-2-ylidene]-1-(4-nitrophenyl)ethanone
The title compound, C14H16N2O3, is an NH-vinylogous amide (enaminone) produced by the reaction of 4-nitrophenacyl bromide with azepane-2-thione. The conformation about the C=C bond [1.3927 (14) Å] is Z, which allows for the formation of an intramolecular N&am...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812032035 |
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doaj-42e00cfb53ed47a285441af5d5e3b5eb2020-11-25T00:17:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-08-01688o2479o247910.1107/S16005368120320352-[(2Z)-Azepan-2-ylidene]-1-(4-nitrophenyl)ethanoneSiyanda T. MthembuLee G. MadeleyCharles B. de KoningJoseph P. MichaelThe title compound, C14H16N2O3, is an NH-vinylogous amide (enaminone) produced by the reaction of 4-nitrophenacyl bromide with azepane-2-thione. The conformation about the C=C bond [1.3927 (14) Å] is Z, which allows for the formation of an intramolecular N—H...O hydrogen bond that leads to an S(6) loop. Inversion-related molecules associate via N—H...O hydrogen bonds to form a 12-membered {...OC3NH}2 synthon.http://scripts.iucr.org/cgi-bin/paper?S1600536812032035 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Siyanda T. Mthembu Lee G. Madeley Charles B. de Koning Joseph P. Michael |
| spellingShingle |
Siyanda T. Mthembu Lee G. Madeley Charles B. de Koning Joseph P. Michael 2-[(2Z)-Azepan-2-ylidene]-1-(4-nitrophenyl)ethanone Acta Crystallographica Section E |
| author_facet |
Siyanda T. Mthembu Lee G. Madeley Charles B. de Koning Joseph P. Michael |
| author_sort |
Siyanda T. Mthembu |
| title |
2-[(2Z)-Azepan-2-ylidene]-1-(4-nitrophenyl)ethanone |
| title_short |
2-[(2Z)-Azepan-2-ylidene]-1-(4-nitrophenyl)ethanone |
| title_full |
2-[(2Z)-Azepan-2-ylidene]-1-(4-nitrophenyl)ethanone |
| title_fullStr |
2-[(2Z)-Azepan-2-ylidene]-1-(4-nitrophenyl)ethanone |
| title_full_unstemmed |
2-[(2Z)-Azepan-2-ylidene]-1-(4-nitrophenyl)ethanone |
| title_sort |
2-[(2z)-azepan-2-ylidene]-1-(4-nitrophenyl)ethanone |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-08-01 |
| description |
The title compound, C14H16N2O3, is an NH-vinylogous amide (enaminone) produced by the reaction of 4-nitrophenacyl bromide with azepane-2-thione. The conformation about the C=C bond [1.3927 (14) Å] is Z, which allows for the formation of an intramolecular N—H...O hydrogen bond that leads to an S(6) loop. Inversion-related molecules associate via N—H...O hydrogen bonds to form a 12-membered {...OC3NH}2 synthon. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812032035 |
| work_keys_str_mv |
AT siyandatmthembu 22zazepan2ylidene14nitrophenylethanone AT leegmadeley 22zazepan2ylidene14nitrophenylethanone AT charlesbdekoning 22zazepan2ylidene14nitrophenylethanone AT josephpmichael 22zazepan2ylidene14nitrophenylethanone |
| _version_ |
1725378971063812096 |