Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent

Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent

Morpholinium fluorochromate(VI), MFC, is easily synthesized by reacting morpholine to an aqueous solution of CrO3 and HF. This reagent selectively oxidizes aryl alcohols to their corresponding aldehydes and ketones under mild conditions. Moreover, it is inert towards aldehydes, ketons, oximes, thiol...

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Main Authors: S. Zahra Sayyed-Alangi, H. Sajjadi-Ghotbabadi, Mohammed T. Baei, Sahar Naderi
Format: Article
Language:English
Published: Hindawi Limited 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/851734
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spelling doaj-42d388526247466a827d68d9d25718872020-11-24T23:50:24ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102011-01-018281581810.1155/2011/851734Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous ReagentS. Zahra Sayyed-Alangi0H. Sajjadi-Ghotbabadi1Mohammed T. Baei2Sahar Naderi3Department of Chemistry, Azadshahr Branch, Islamic Azad University, Azadshahr, Golestan, IranDepartment of Chemistry, Azadshahr Branch, Islamic Azad University, Azadshahr, Golestan, IranDepartment of Chemistry, Azadshahr Branch, Islamic Azad University, Azadshahr, Golestan, IranDepartment of Chemistry, Azadshahr Branch, Islamic Azad University, Azadshahr, Golestan, IranMorpholinium fluorochromate(VI), MFC, is easily synthesized by reacting morpholine to an aqueous solution of CrO3 and HF. This reagent selectively oxidizes aryl alcohols to their corresponding aldehydes and ketones under mild conditions. Moreover, it is inert towards aldehydes, ketons, oximes, thiols, sulfids, phenols, pyrans, trimethylsilanes, malonates and thioacetamides. The durability, reaction rate, ease of filtration and efficiency of MFC are considerably increased upon its absorption on silica gel.http://dx.doi.org/10.1155/2011/851734
collection DOAJ
language English
format Article
sources DOAJ
author S. Zahra Sayyed-Alangi
H. Sajjadi-Ghotbabadi
Mohammed T. Baei
Sahar Naderi
spellingShingle S. Zahra Sayyed-Alangi
H. Sajjadi-Ghotbabadi
Mohammed T. Baei
Sahar Naderi
Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent
E-Journal of Chemistry
author_facet S. Zahra Sayyed-Alangi
H. Sajjadi-Ghotbabadi
Mohammed T. Baei
Sahar Naderi
author_sort S. Zahra Sayyed-Alangi
title Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent
title_short Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent
title_full Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent
title_fullStr Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent
title_full_unstemmed Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent
title_sort oxidation of aryl alcohols by morpholinium fluorochromate(vi) on silica gel, a selective and efficient heterogeneous reagent
publisher Hindawi Limited
series E-Journal of Chemistry
issn 0973-4945
2090-9810
publishDate 2011-01-01
description Morpholinium fluorochromate(VI), MFC, is easily synthesized by reacting morpholine to an aqueous solution of CrO3 and HF. This reagent selectively oxidizes aryl alcohols to their corresponding aldehydes and ketones under mild conditions. Moreover, it is inert towards aldehydes, ketons, oximes, thiols, sulfids, phenols, pyrans, trimethylsilanes, malonates and thioacetamides. The durability, reaction rate, ease of filtration and efficiency of MFC are considerably increased upon its absorption on silica gel.
url http://dx.doi.org/10.1155/2011/851734
work_keys_str_mv AT szahrasayyedalangi oxidationofarylalcoholsbymorpholiniumfluorochromatevionsilicagelaselectiveandefficientheterogeneousreagent
AT hsajjadighotbabadi oxidationofarylalcoholsbymorpholiniumfluorochromatevionsilicagelaselectiveandefficientheterogeneousreagent
AT mohammedtbaei oxidationofarylalcoholsbymorpholiniumfluorochromatevionsilicagelaselectiveandefficientheterogeneousreagent
AT saharnaderi oxidationofarylalcoholsbymorpholiniumfluorochromatevionsilicagelaselectiveandefficientheterogeneousreagent
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