Catalytic Performances of Platinum Containing PLLA Macrocomplex in the Hydrogenation of α,β-Unsaturated Carbonyl Compounds

The synthesis of a bipyridine poly(lactic acid) carboxylic end-capped macroligand coordinated to a platinum center was reported. The reaction between the metal ion and the polymeric ligand was run in a very efficient way through a one-step synthesis and the complex was tested for selective hydrogena...

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Main Authors:	Mattia Bartoli, Luca Rosi, Benedetta Mini, Giorgio Petrucci, Elisa Passaglia, Marco Frediani
Format:	Article
Language:	English
Published:	MDPI AG 2019-08-01
Series:	Applied Sciences
Subjects:	poly(lactic acid) hydrogenation polymer functionalization macroligands
Online Access:	https://www.mdpi.com/2076-3417/9/16/3243

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spelling	doaj-428cad8e692345e9ba4ecb09326fc0de2020-11-24T21:25:12ZengMDPI AGApplied Sciences2076-34172019-08-01916324310.3390/app9163243app9163243Catalytic Performances of Platinum Containing PLLA Macrocomplex in the Hydrogenation of α,β-Unsaturated Carbonyl CompoundsMattia Bartoli0Luca Rosi1Benedetta Mini2Giorgio Petrucci3Elisa Passaglia4Marco Frediani5Department of Chemistry “Ugo Schiff”, University of Florence, Via della Lastruccia 3–13, 50019 Sesto Fiorentino, ItalyDepartment of Chemistry “Ugo Schiff”, University of Florence, Via della Lastruccia 3–13, 50019 Sesto Fiorentino, ItalyDepartment of Chemistry “Ugo Schiff”, University of Florence, Via della Lastruccia 3–13, 50019 Sesto Fiorentino, ItalyDepartment of Chemistry “Ugo Schiff”, University of Florence, Via della Lastruccia 3–13, 50019 Sesto Fiorentino, ItalyItalian National Council for Research - Institute for the Chemistry of OrganoMetallic Compounds, Secondary Station of Pisa (CNR-ICCOM SS Pisa), Via Moruzzi 1, 56124 Pisa, ItalyDepartment of Chemistry “Ugo Schiff”, University of Florence, Via della Lastruccia 3–13, 50019 Sesto Fiorentino, ItalyThe synthesis of a bipyridine poly(lactic acid) carboxylic end-capped macroligand coordinated to a platinum center was reported. The reaction between the metal ion and the polymeric ligand was run in a very efficient way through a one-step synthesis and the complex was tested for selective hydrogenation of α,β-carbonyl compounds. High selectivity was proven for double bond hydrogenation of 2-cyclohexen-1-one (up to 99%) and the production of 1-butanol from (E)-but-2-enal. Moreover, the catalytic system was still active after three catalytic cycles.https://www.mdpi.com/2076-3417/9/16/3243poly(lactic acid)hydrogenationpolymer functionalizationmacroligands
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Mattia Bartoli Luca Rosi Benedetta Mini Giorgio Petrucci Elisa Passaglia Marco Frediani
spellingShingle	Mattia Bartoli Luca Rosi Benedetta Mini Giorgio Petrucci Elisa Passaglia Marco Frediani Catalytic Performances of Platinum Containing PLLA Macrocomplex in the Hydrogenation of α,β-Unsaturated Carbonyl Compounds Applied Sciences poly(lactic acid) hydrogenation polymer functionalization macroligands
author_facet	Mattia Bartoli Luca Rosi Benedetta Mini Giorgio Petrucci Elisa Passaglia Marco Frediani
author_sort	Mattia Bartoli
title	Catalytic Performances of Platinum Containing PLLA Macrocomplex in the Hydrogenation of α,β-Unsaturated Carbonyl Compounds
title_short	Catalytic Performances of Platinum Containing PLLA Macrocomplex in the Hydrogenation of α,β-Unsaturated Carbonyl Compounds
title_full	Catalytic Performances of Platinum Containing PLLA Macrocomplex in the Hydrogenation of α,β-Unsaturated Carbonyl Compounds
title_fullStr	Catalytic Performances of Platinum Containing PLLA Macrocomplex in the Hydrogenation of α,β-Unsaturated Carbonyl Compounds
title_full_unstemmed	Catalytic Performances of Platinum Containing PLLA Macrocomplex in the Hydrogenation of α,β-Unsaturated Carbonyl Compounds
title_sort	catalytic performances of platinum containing plla macrocomplex in the hydrogenation of α,β-unsaturated carbonyl compounds
publisher	MDPI AG
series	Applied Sciences
issn	2076-3417
publishDate	2019-08-01
description	The synthesis of a bipyridine poly(lactic acid) carboxylic end-capped macroligand coordinated to a platinum center was reported. The reaction between the metal ion and the polymeric ligand was run in a very efficient way through a one-step synthesis and the complex was tested for selective hydrogenation of α,β-carbonyl compounds. High selectivity was proven for double bond hydrogenation of 2-cyclohexen-1-one (up to 99%) and the production of 1-butanol from (E)-but-2-enal. Moreover, the catalytic system was still active after three catalytic cycles.
topic	poly(lactic acid) hydrogenation polymer functionalization macroligands
url	https://www.mdpi.com/2076-3417/9/16/3243
work_keys_str_mv	AT mattiabartoli catalyticperformancesofplatinumcontainingpllamacrocomplexinthehydrogenationofabunsaturatedcarbonylcompounds AT lucarosi catalyticperformancesofplatinumcontainingpllamacrocomplexinthehydrogenationofabunsaturatedcarbonylcompounds AT benedettamini catalyticperformancesofplatinumcontainingpllamacrocomplexinthehydrogenationofabunsaturatedcarbonylcompounds AT giorgiopetrucci catalyticperformancesofplatinumcontainingpllamacrocomplexinthehydrogenationofabunsaturatedcarbonylcompounds AT elisapassaglia catalyticperformancesofplatinumcontainingpllamacrocomplexinthehydrogenationofabunsaturatedcarbonylcompounds AT marcofrediani catalyticperformancesofplatinumcontainingpllamacrocomplexinthehydrogenationofabunsaturatedcarbonylcompounds
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Catalytic Performances of Platinum Containing PLLA Macrocomplex in the Hydrogenation of α,β-Unsaturated Carbonyl Compounds

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