4-[5-(4-Fluorophenyl)-1-(4-phenyl-1,3-thiazol-2-yl)-4,5-dihydro-1H-pyrazol-3-yl]-5-methyl-1-(4-methylphenyl)-1H-1,2,3-triazole

4-[5-(4-Fluorophenyl)-1-(4-phenyl-1,3-thiazol-2-yl)-4,5-dihydro-1H-pyrazol-3-yl]-5-methyl-1-(4-methylphenyl)-1H-1,2,3-triazole

In the title compound, C28H23FN6S, the pyrazole ring adopts an envelope conformation, with the methine C atom being the flap atom. With respect to this ring, the 2-thienyl, triazole and fluorobenzene rings are approximately coplanar, coplanar and perpendicular, respectively [dihedral angles = 8.56&a...

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Main Authors: Bakr F. Abdel-Wahab, Seik Weng Ng, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2013-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813008179
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spelling doaj-4264fd596b0e442185818cbfb3d0d2b82020-11-25T01:35:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-04-01694o618o61810.1107/S16005368130081794-[5-(4-Fluorophenyl)-1-(4-phenyl-1,3-thiazol-2-yl)-4,5-dihydro-1H-pyrazol-3-yl]-5-methyl-1-(4-methylphenyl)-1H-1,2,3-triazoleBakr F. Abdel-WahabSeik Weng NgEdward R. T. TiekinkIn the title compound, C28H23FN6S, the pyrazole ring adopts an envelope conformation, with the methine C atom being the flap atom. With respect to this ring, the 2-thienyl, triazole and fluorobenzene rings are approximately coplanar, coplanar and perpendicular, respectively [dihedral angles = 8.56 (17), 6.03 (19) and 73.1 (2)°, respectively] so that to a first approximation the molecule has a T-shape. In the crystal, molecules are consolidated into a three-dimensional architecture by C—H...F (involving a bifurcated F atom), C—H...S and C—H...π interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536813008179
collection DOAJ
language English
format Article
sources DOAJ
author Bakr F. Abdel-Wahab
Seik Weng Ng
Edward R. T. Tiekink
spellingShingle Bakr F. Abdel-Wahab
Seik Weng Ng
Edward R. T. Tiekink
4-[5-(4-Fluorophenyl)-1-(4-phenyl-1,3-thiazol-2-yl)-4,5-dihydro-1H-pyrazol-3-yl]-5-methyl-1-(4-methylphenyl)-1H-1,2,3-triazole
Acta Crystallographica Section E
author_facet Bakr F. Abdel-Wahab
Seik Weng Ng
Edward R. T. Tiekink
author_sort Bakr F. Abdel-Wahab
title 4-[5-(4-Fluorophenyl)-1-(4-phenyl-1,3-thiazol-2-yl)-4,5-dihydro-1H-pyrazol-3-yl]-5-methyl-1-(4-methylphenyl)-1H-1,2,3-triazole
title_short 4-[5-(4-Fluorophenyl)-1-(4-phenyl-1,3-thiazol-2-yl)-4,5-dihydro-1H-pyrazol-3-yl]-5-methyl-1-(4-methylphenyl)-1H-1,2,3-triazole
title_full 4-[5-(4-Fluorophenyl)-1-(4-phenyl-1,3-thiazol-2-yl)-4,5-dihydro-1H-pyrazol-3-yl]-5-methyl-1-(4-methylphenyl)-1H-1,2,3-triazole
title_fullStr 4-[5-(4-Fluorophenyl)-1-(4-phenyl-1,3-thiazol-2-yl)-4,5-dihydro-1H-pyrazol-3-yl]-5-methyl-1-(4-methylphenyl)-1H-1,2,3-triazole
title_full_unstemmed 4-[5-(4-Fluorophenyl)-1-(4-phenyl-1,3-thiazol-2-yl)-4,5-dihydro-1H-pyrazol-3-yl]-5-methyl-1-(4-methylphenyl)-1H-1,2,3-triazole
title_sort 4-[5-(4-fluorophenyl)-1-(4-phenyl-1,3-thiazol-2-yl)-4,5-dihydro-1h-pyrazol-3-yl]-5-methyl-1-(4-methylphenyl)-1h-1,2,3-triazole
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-04-01
description In the title compound, C28H23FN6S, the pyrazole ring adopts an envelope conformation, with the methine C atom being the flap atom. With respect to this ring, the 2-thienyl, triazole and fluorobenzene rings are approximately coplanar, coplanar and perpendicular, respectively [dihedral angles = 8.56 (17), 6.03 (19) and 73.1 (2)°, respectively] so that to a first approximation the molecule has a T-shape. In the crystal, molecules are consolidated into a three-dimensional architecture by C—H...F (involving a bifurcated F atom), C—H...S and C—H...π interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813008179
work_keys_str_mv AT bakrfabdelwahab 454fluorophenyl14phenyl13thiazol2yl45dihydro1hpyrazol3yl5methyl14methylphenyl1h123triazole
AT seikwengng 454fluorophenyl14phenyl13thiazol2yl45dihydro1hpyrazol3yl5methyl14methylphenyl1h123triazole
AT edwardrttiekink 454fluorophenyl14phenyl13thiazol2yl45dihydro1hpyrazol3yl5methyl14methylphenyl1h123triazole
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