[μ-10,22-Dichloro-3,6-bis(2-furylmethyl)-3,6,14,18-tetraazatricyclo[18.3.1.18,12]pentacosa-1(23),8,10,12(25),13,18,20(24),21-octaene-24,25-diolato-κ8N3,N6,O24,O25:N14,N18,O24:O25]bis[chloridocopper(II)] acetonitrile solvate
The title compound, [Cu2(C31H30Cl2N4O4)Cl2]·CH3CN, was synthesized by cyclocondensation between N,N′-bis(2-furyl)-N,N′-bis(3-formyl-5-chlorosalicylaldehyde)ethylenediamine and 1,3-diaminopropane in the presence of CuII ions. It is an unsymmetrical dinuclear CuII complex....
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-02-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809000166 |
| Summary: | The title compound, [Cu2(C31H30Cl2N4O4)Cl2]·CH3CN, was synthesized by cyclocondensation between N,N′-bis(2-furyl)-N,N′-bis(3-formyl-5-chlorosalicylaldehyde)ethylenediamine and 1,3-diaminopropane in the presence of CuII ions. It is an unsymmetrical dinuclear CuII complex. The coordination geometry for each CuII atom can be discribed as distorted square-pyramidal. The two Cu atoms are bridged by two phenolate O atoms with a Cu...Cu distance of 3.0274 (9) Å. |
|---|---|
| ISSN: | 1600-5368 |