Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion

Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion

A new organic–inorganic hybrid compound, pentamorpholinium hexahydrogen hexamolybdoferrate(III) sulfate 3.5-hydrate, (C4H10NO)5[FeIII(OH)6Mo6O18](SO4)·3.5H2O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson β-type with a central FeIII ion. Three of five c...

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Bibliographic Details
Main Authors: Tamara J. Lukianova, Vasyl Kinzhybalo, Adam Pietraszko
Format: Article
Language:English
Published: International Union of Crystallography 2015-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
polyoxidomolybdate
Anderson-type anion
organic–inorganic hybrid
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015019246
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spelling doaj-42390221f196486e90562025e8ba0e342020-11-25T00:00:29ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-11-0171111345134810.1107/S2056989015019246wm5221Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanionTamara J. Lukianova0Vasyl Kinzhybalo1Adam Pietraszko2Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Okolna str. 2, PO Box 1410, 50-950 Wroclaw, PolandInstitute of Low Temperature and Structure Research, Polish Academy of Sciences, Okolna str. 2, PO Box 1410, 50-950 Wroclaw, PolandInstitute of Low Temperature and Structure Research, Polish Academy of Sciences, Okolna str. 2, PO Box 1410, 50-950 Wroclaw, PolandA new organic–inorganic hybrid compound, pentamorpholinium hexahydrogen hexamolybdoferrate(III) sulfate 3.5-hydrate, (C4H10NO)5[FeIII(OH)6Mo6O18](SO4)·3.5H2O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson β-type with a central FeIII ion. Three of five crystallographically independent morpholinium cations are disordered over two sets of sites. An intricate network of intermolecular N—H...O and O—H...O interactions between cations, POMs, sulfate anions and non-coordinating water molecules creates a three-dimensional network structure.http://scripts.iucr.org/cgi-bin/paper?S2056989015019246crystal structurepolyoxidomolybdateAnderson-type anionorganic–inorganic hybrid
collection DOAJ
language English
format Article
sources DOAJ
author Tamara J. Lukianova
Vasyl Kinzhybalo
Adam Pietraszko
spellingShingle Tamara J. Lukianova
Vasyl Kinzhybalo
Adam Pietraszko
Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
polyoxidomolybdate
Anderson-type anion
organic–inorganic hybrid
author_facet Tamara J. Lukianova
Vasyl Kinzhybalo
Adam Pietraszko
author_sort Tamara J. Lukianova
title Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion
title_short Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion
title_full Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion
title_fullStr Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion
title_full_unstemmed Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion
title_sort crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type anderson polyanion
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2015-11-01
description A new organic–inorganic hybrid compound, pentamorpholinium hexahydrogen hexamolybdoferrate(III) sulfate 3.5-hydrate, (C4H10NO)5[FeIII(OH)6Mo6O18](SO4)·3.5H2O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson β-type with a central FeIII ion. Three of five crystallographically independent morpholinium cations are disordered over two sets of sites. An intricate network of intermolecular N—H...O and O—H...O interactions between cations, POMs, sulfate anions and non-coordinating water molecules creates a three-dimensional network structure.
topic crystal structure
polyoxidomolybdate
Anderson-type anion
organic–inorganic hybrid
url http://scripts.iucr.org/cgi-bin/paper?S2056989015019246
work_keys_str_mv AT tamarajlukianova crystalstructureofanorganicinorganichybridcompoundbasedonmorpholiniumcationsandabtypeandersonpolyanion
AT vasylkinzhybalo crystalstructureofanorganicinorganichybridcompoundbasedonmorpholiniumcationsandabtypeandersonpolyanion
AT adampietraszko crystalstructureofanorganicinorganichybridcompoundbasedonmorpholiniumcationsandabtypeandersonpolyanion
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