Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion

Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion

A new organic–inorganic hybrid compound, pentamorpholinium hexahydrogen hexamolybdoferrate(III) sulfate 3.5-hydrate, (C4H10NO)5[FeIII(OH)6Mo6O18](SO4)·3.5H2O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson β-type with a central FeIII ion. Three of five c...

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Bibliographic Details
Main Authors: Tamara J. Lukianova, Vasyl Kinzhybalo, Adam Pietraszko
Format: Article
Language:English
Published: International Union of Crystallography 2015-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
polyoxidomolybdate
Anderson-type anion
organic–inorganic hybrid
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015019246
Description
Summary:A new organic–inorganic hybrid compound, pentamorpholinium hexahydrogen hexamolybdoferrate(III) sulfate 3.5-hydrate, (C4H10NO)5[FeIII(OH)6Mo6O18](SO4)·3.5H2O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson β-type with a central FeIII ion. Three of five crystallographically independent morpholinium cations are disordered over two sets of sites. An intricate network of intermolecular N—H...O and O—H...O interactions between cations, POMs, sulfate anions and non-coordinating water molecules creates a three-dimensional network structure.
ISSN:2056-9890

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