Fabrication of Poly(butylene succinate)/Carbon Black Nanocomposite Foams with Good Electrical Conductivity and High Strength by a Supercritical CO₂ Foaming Process

• Main Authors: Zhou Chen, Junfeng Hu, Jiajun Ju, Tairong Kuang
• Format: Article
• Language: English
• Published: MDPI AG 2019-11-01
• Series: Polymers
• Subjects: poly(butylene succinate) (pbs); carbon black (cb); solid-state scco₂ foaming; lightweight; good electrical conductivity
• Online Access: https://www.mdpi.com/2073-4360/11/11/1852

Lightweight, high-strength and electrically conductive poly(butylene succinate) (PBS)/ carbon black (CB) nanocomposite foams with a density of 0.107−0.344 g/cm³ were successfully fabricated by a solid-state supercritical CO₂ (ScCO₂) foaming process. The morphology, thermal and dynamic mechanical properties, and rheological behavior of the PBS/CB nanocomposites were studied. The results indicate that the CB nanofiller was well dispersed in the PBS matrix and the presence of a proper CB nanofiller can accelerate the rate of crystallization, improve the thermal stability, enhance the stiffness, and increase the complex viscosity of PBS/CB nanocomposites. These improved properties were found to play an important role in the foaming process. The results from foaming experiments showed that the PBS/CB nanocomposite foams had a much smaller cell size, a higher cell density, and a more uniform cell morphology as compared to neat PBS foams. Furthermore, the PBS/CB nanocomposite foams also possessed low density (0.107−0.344 g/cm³), good electrical conductivity (~0.45 S/cm at 1.87 vol % CB loading), and improved compressive strength (108% increase), which enables them to be used as lightweight and high-strength functional materials.