Bis(2,4-dimethylpyridinium) tetrabromidomercurate(II)

Bis(2,4-dimethylpyridinium) tetrabromidomercurate(II)

The asymmetric unit of the title compound, (C7H10N)2[HgBr4], consists of one cation and one half-anion, bisected by a twofold rotation axis passing through the metal atom. The anion exhibits a distorted tetrahedral arrangement about the HgII atom. In the crystal, the cations and anions are linked by...

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Main Authors: Rawhi Al-Far, Salim F. Haddad, Basem F. Ali
Format: Article
Language:English
Published: International Union of Crystallography 2012-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812046788
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spelling doaj-419040c649734823bd365ad8542a92512020-11-24T21:25:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812m1499m149910.1107/S1600536812046788Bis(2,4-dimethylpyridinium) tetrabromidomercurate(II)Rawhi Al-FarSalim F. HaddadBasem F. AliThe asymmetric unit of the title compound, (C7H10N)2[HgBr4], consists of one cation and one half-anion, bisected by a twofold rotation axis passing through the metal atom. The anion exhibits a distorted tetrahedral arrangement about the HgII atom. In the crystal, the cations and anions are linked by N—H...Br hydrogen-bonding interactions along [010]. Cation–cation π–π stacking and Br...Br intermolecular interactions are absent.http://scripts.iucr.org/cgi-bin/paper?S1600536812046788
collection DOAJ
language English
format Article
sources DOAJ
author Rawhi Al-Far
Salim F. Haddad
Basem F. Ali
spellingShingle Rawhi Al-Far
Salim F. Haddad
Basem F. Ali
Bis(2,4-dimethylpyridinium) tetrabromidomercurate(II)
Acta Crystallographica Section E
author_facet Rawhi Al-Far
Salim F. Haddad
Basem F. Ali
author_sort Rawhi Al-Far
title Bis(2,4-dimethylpyridinium) tetrabromidomercurate(II)
title_short Bis(2,4-dimethylpyridinium) tetrabromidomercurate(II)
title_full Bis(2,4-dimethylpyridinium) tetrabromidomercurate(II)
title_fullStr Bis(2,4-dimethylpyridinium) tetrabromidomercurate(II)
title_full_unstemmed Bis(2,4-dimethylpyridinium) tetrabromidomercurate(II)
title_sort bis(2,4-dimethylpyridinium) tetrabromidomercurate(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-12-01
description The asymmetric unit of the title compound, (C7H10N)2[HgBr4], consists of one cation and one half-anion, bisected by a twofold rotation axis passing through the metal atom. The anion exhibits a distorted tetrahedral arrangement about the HgII atom. In the crystal, the cations and anions are linked by N—H...Br hydrogen-bonding interactions along [010]. Cation–cation π–π stacking and Br...Br intermolecular interactions are absent.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812046788
work_keys_str_mv AT rawhialfar bis24dimethylpyridiniumtetrabromidomercurateii
AT salimfhaddad bis24dimethylpyridiniumtetrabromidomercurateii
AT basemfali bis24dimethylpyridiniumtetrabromidomercurateii
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