Improving Hydrogen Embrittlement Resistance of Hot-Stamped 1500 MPa Steel Parts That Have Undergone a Q&P Treatment by the Design of Retained Austenite and Martensite Matrix

Hydrogen embrittlement is one of the largest obstacles against the commercialisation of ultra-high strength quenching and partitioning (Q&P) steels with ultimate tensile strength over 1500 MPa, including the hot stamped steel parts that have undergone a Q&P treatment. In this work, the influ...

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Main Authors: Zhou Wang, Mingxin Huang
Format: Article
Language:English
Published: MDPI AG 2020-11-01
Series:Metals
Subjects:
amp
Online Access:https://www.mdpi.com/2075-4701/10/12/1585
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spelling doaj-418e2d85d3ea470da86decf018866aee2020-11-27T08:12:27ZengMDPI AGMetals2075-47012020-11-01101585158510.3390/met10121585Improving Hydrogen Embrittlement Resistance of Hot-Stamped 1500 MPa Steel Parts That Have Undergone a Q&P Treatment by the Design of Retained Austenite and Martensite MatrixZhou Wang0Mingxin Huang1Department of Mechanical Engineering, The University of Hong Kong, Pokfulam Road, Hong Kong 999077, ChinaDepartment of Mechanical Engineering, The University of Hong Kong, Pokfulam Road, Hong Kong 999077, ChinaHydrogen embrittlement is one of the largest obstacles against the commercialisation of ultra-high strength quenching and partitioning (Q&P) steels with ultimate tensile strength over 1500 MPa, including the hot stamped steel parts that have undergone a Q&P treatment. In this work, the influence of partitioning temperature on hydrogen embrittlement of ultra-high strength Q&P steels is studied by pre-charged tensile tests with both dog-bone and notched samples. It is found that hydrogen embrittlement resistance is enhanced by the higher partitioning temperature. Then, the hydrogen embrittlement mechanism is analysed in terms of hydrogen, retained austenite, and martensite matrix. Thermal desorption analysis (TDA) shows that the hydrogen trapping properties are similar in the Q&P steels, which cannot explain the enhancement of hydrogen embrittlement resistance. On the contrary, it is found that the relatively low retained austenite stability after the higher temperature partitioning ensures more sufficient TRIP effect before hydrogen-induced fracture. Additionally, dislocation recovery and solute carbon depletion at the higher partitioning temperature can reduce the flow stress of the martensite matrix, improving its intrinsic toughness and reducing its hydrogen sensitivity, both of which result in the higher hydrogen embrittlement resistance.https://www.mdpi.com/2075-4701/10/12/1585quenching and partitioning (Q&ampampP) steelhydrogen embrittlementretained austenitemartensite matrix
collection DOAJ
language English
format Article
sources DOAJ
author Zhou Wang
Mingxin Huang
spellingShingle Zhou Wang
Mingxin Huang
Improving Hydrogen Embrittlement Resistance of Hot-Stamped 1500 MPa Steel Parts That Have Undergone a Q&P Treatment by the Design of Retained Austenite and Martensite Matrix
Metals
quenching and partitioning (Q&amp
amp
P) steel
hydrogen embrittlement
retained austenite
martensite matrix
author_facet Zhou Wang
Mingxin Huang
author_sort Zhou Wang
title Improving Hydrogen Embrittlement Resistance of Hot-Stamped 1500 MPa Steel Parts That Have Undergone a Q&P Treatment by the Design of Retained Austenite and Martensite Matrix
title_short Improving Hydrogen Embrittlement Resistance of Hot-Stamped 1500 MPa Steel Parts That Have Undergone a Q&P Treatment by the Design of Retained Austenite and Martensite Matrix
title_full Improving Hydrogen Embrittlement Resistance of Hot-Stamped 1500 MPa Steel Parts That Have Undergone a Q&P Treatment by the Design of Retained Austenite and Martensite Matrix
title_fullStr Improving Hydrogen Embrittlement Resistance of Hot-Stamped 1500 MPa Steel Parts That Have Undergone a Q&P Treatment by the Design of Retained Austenite and Martensite Matrix
title_full_unstemmed Improving Hydrogen Embrittlement Resistance of Hot-Stamped 1500 MPa Steel Parts That Have Undergone a Q&P Treatment by the Design of Retained Austenite and Martensite Matrix
title_sort improving hydrogen embrittlement resistance of hot-stamped 1500 mpa steel parts that have undergone a q&p treatment by the design of retained austenite and martensite matrix
publisher MDPI AG
series Metals
issn 2075-4701
publishDate 2020-11-01
description Hydrogen embrittlement is one of the largest obstacles against the commercialisation of ultra-high strength quenching and partitioning (Q&P) steels with ultimate tensile strength over 1500 MPa, including the hot stamped steel parts that have undergone a Q&P treatment. In this work, the influence of partitioning temperature on hydrogen embrittlement of ultra-high strength Q&P steels is studied by pre-charged tensile tests with both dog-bone and notched samples. It is found that hydrogen embrittlement resistance is enhanced by the higher partitioning temperature. Then, the hydrogen embrittlement mechanism is analysed in terms of hydrogen, retained austenite, and martensite matrix. Thermal desorption analysis (TDA) shows that the hydrogen trapping properties are similar in the Q&P steels, which cannot explain the enhancement of hydrogen embrittlement resistance. On the contrary, it is found that the relatively low retained austenite stability after the higher temperature partitioning ensures more sufficient TRIP effect before hydrogen-induced fracture. Additionally, dislocation recovery and solute carbon depletion at the higher partitioning temperature can reduce the flow stress of the martensite matrix, improving its intrinsic toughness and reducing its hydrogen sensitivity, both of which result in the higher hydrogen embrittlement resistance.
topic quenching and partitioning (Q&amp
amp
P) steel
hydrogen embrittlement
retained austenite
martensite matrix
url https://www.mdpi.com/2075-4701/10/12/1585
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