Near-UV light assisted green reduction of graphene oxide films through l-ascorbic acid

• Main Authors: Jaime Regis, Sebastian Vargas, Andrea Irigoyen, Elsa Bramasco-Rivera, Jose L. Bañuelos, Luis C. Delfin, Anabel Renteria, Ulises Martinez, Tommy Rockward, Yirong Lin
• Format: Article
• Language: English
• Published: Taylor & Francis Group 2021-01-01
• Series: International Journal of Smart and Nano Materials
• Subjects: graphene oxide films; green reduction; near ultraviolet light; l-ascorbic acid; wide-angle x-ray scattering
• Online Access: http://dx.doi.org/10.1080/19475411.2021.1887396
• ISSN: 1947-5411; 1947-542X

Recent studies have highlighted the effects of various stimuli on the chemical reduction of graphene oxide (GO) through green reductant L-ascorbic acid (L-AA); however, the combination of near ultraviolet (NUV) light to increase the reduction rate has yet to be thoroughly explored. In this study, drop-casted GO films were subjected to chemical reduction through L-AA with various levels of exposure under 405 nm NUV radiation. The structure and uniformity of GO stackings that form the film were characterized through scanning electron microscopy (SEM) and wide-angle x-ray scattering (WAXS). Additionally, WAXS was used to track the removal of oxygen-containing functional groups along with Fourier-transform infrared (FT-IR) spectroscopy and x-ray photoelectron spectroscopy (XPS) as a function of L-AA and NUV light exposure times. XPS results demonstrated that the interaction between L-AA and NUV exposure has a significant effect on the reduction of films. Furthermore, the results that yielded the highest reduction (C-C bond concentration of 60.7%) were the longest L-AA and NUV light exposure times (48 hours and 3 hours, respectively). This report provides a study on the effects of NUV on the green reduction of GO films through L-AA with potential application in solar energy and chemical sensing applications.