On the mechanism of action of gated molecular baskets: The synchronicity of the revolving motion of gates and in/out trafficking of guests

On the mechanism of action of gated molecular baskets: The synchronicity of the revolving motion of gates and in/out trafficking of guests

We used dynamic 1H NMR spectroscopic methods to examine the kinetics and thermodynamics of CH3CCl3 (2) entering and leaving the gated molecular basket 1. We found that the encapsulation is first-order in basket 1 and guest 2, while the decomplexation is zeroth-order in the guest. Importantly, the in...

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Bibliographic Details
Main Authors: Keith Hermann, Stephen Rieth, Hashem A. Taha, Bao-Yu Wang, Christopher M. Hadad, Jovica D. Badjić
Format: Article
Language:English
Published: Beilstein-Institut 2012-01-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
dynamic NMR
host–guest chemistry
linear free-energy relationships
molecular encapsulation
recognition kinetics
Online Access:https://doi.org/10.3762/bjoc.8.9

Internet

https://doi.org/10.3762/bjoc.8.9

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