Site-selective doping of ordered charge states in magnetite

Charge ordering in magnetite is an important example of the complex behaviour that emerges in transition metal oxides. Here the authors show that doping causes selective oxidation of one site in the established trimeron pattern, introducing an additional charge-ordered structure.

Bibliographic Details
Main Authors: E. Pachoud, J. Cumby, G. Perversi, J. P. Wright, J. P. Attfield
Format: Article
Language:English
Published: Nature Publishing Group 2020-04-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-020-15504-5
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spelling doaj-40eb1e0370a84121a0527f52a82055972021-05-11T08:42:29ZengNature Publishing GroupNature Communications2041-17232020-04-011111510.1038/s41467-020-15504-5Site-selective doping of ordered charge states in magnetiteE. Pachoud0J. Cumby1G. Perversi2J. P. Wright3J. P. Attfield4Centre for Science at Extreme Conditions and School of Chemistry, University of EdinburghCentre for Science at Extreme Conditions and School of Chemistry, University of EdinburghCentre for Science at Extreme Conditions and School of Chemistry, University of EdinburghEuropean Synchrotron Radiation FacilityCentre for Science at Extreme Conditions and School of Chemistry, University of EdinburghCharge ordering in magnetite is an important example of the complex behaviour that emerges in transition metal oxides. Here the authors show that doping causes selective oxidation of one site in the established trimeron pattern, introducing an additional charge-ordered structure.https://doi.org/10.1038/s41467-020-15504-5
collection DOAJ
language English
format Article
sources DOAJ
author E. Pachoud
J. Cumby
G. Perversi
J. P. Wright
J. P. Attfield
spellingShingle E. Pachoud
J. Cumby
G. Perversi
J. P. Wright
J. P. Attfield
Site-selective doping of ordered charge states in magnetite
Nature Communications
author_facet E. Pachoud
J. Cumby
G. Perversi
J. P. Wright
J. P. Attfield
author_sort E. Pachoud
title Site-selective doping of ordered charge states in magnetite
title_short Site-selective doping of ordered charge states in magnetite
title_full Site-selective doping of ordered charge states in magnetite
title_fullStr Site-selective doping of ordered charge states in magnetite
title_full_unstemmed Site-selective doping of ordered charge states in magnetite
title_sort site-selective doping of ordered charge states in magnetite
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2020-04-01
description Charge ordering in magnetite is an important example of the complex behaviour that emerges in transition metal oxides. Here the authors show that doping causes selective oxidation of one site in the established trimeron pattern, introducing an additional charge-ordered structure.
url https://doi.org/10.1038/s41467-020-15504-5
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AT gperversi siteselectivedopingoforderedchargestatesinmagnetite
AT jpwright siteselectivedopingoforderedchargestatesinmagnetite
AT jpattfield siteselectivedopingoforderedchargestatesinmagnetite
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