<b>Reaction of propargyltrimethylsilane magnesium bromide with aldimines: Synthesis of 1-(alkylamino)-2-(trimethylsilyl)but-3-yne</b>
The reaction of propargylsilane magnesium bromide with aldimines provides in some cases, an isomeric mixture of three acetylenic amines <b>1</b>, <b>2</b>, <b>3</b> (<b>1</b> and <b>2</b>, as major products). The reaction has great potentia...
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| Format: | Article |
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Chemical Society of Ethiopia
2002-12-01
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| Series: | Bulletin of the Chemical Society of Ethiopia |
| Online Access: | http://www.ajol.info/index.php/bcse/article/view/20940 |
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doaj-40e2a029b5eb4b9c80352c72ea21b8cf2020-11-24T22:32:54ZengChemical Society of EthiopiaBulletin of the Chemical Society of Ethiopia1011-39241726-801X2002-12-01162169174<b>Reaction of propargyltrimethylsilane magnesium bromide with aldimines: Synthesis of 1-(alkylamino)-2-(trimethylsilyl)but-3-yne</b>L. Mbaze Meva’aJ.C. NdomE. Ngeufa.HappiThe reaction of propargylsilane magnesium bromide with aldimines provides in some cases, an isomeric mixture of three acetylenic amines <b>1</b>, <b>2</b>, <b>3</b> (<b>1</b> and <b>2</b>, as major products). The reaction has great potential and has been exploited for an efficient synthesis of the pure amine <b>2</b>.http://www.ajol.info/index.php/bcse/article/view/20940 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
L. Mbaze Meva’a J.C. Ndom E. Ngeufa.Happi |
| spellingShingle |
L. Mbaze Meva’a J.C. Ndom E. Ngeufa.Happi <b>Reaction of propargyltrimethylsilane magnesium bromide with aldimines: Synthesis of 1-(alkylamino)-2-(trimethylsilyl)but-3-yne</b> Bulletin of the Chemical Society of Ethiopia |
| author_facet |
L. Mbaze Meva’a J.C. Ndom E. Ngeufa.Happi |
| author_sort |
L. Mbaze Meva’a |
| title |
<b>Reaction of propargyltrimethylsilane magnesium bromide with aldimines: Synthesis of 1-(alkylamino)-2-(trimethylsilyl)but-3-yne</b> |
| title_short |
<b>Reaction of propargyltrimethylsilane magnesium bromide with aldimines: Synthesis of 1-(alkylamino)-2-(trimethylsilyl)but-3-yne</b> |
| title_full |
<b>Reaction of propargyltrimethylsilane magnesium bromide with aldimines: Synthesis of 1-(alkylamino)-2-(trimethylsilyl)but-3-yne</b> |
| title_fullStr |
<b>Reaction of propargyltrimethylsilane magnesium bromide with aldimines: Synthesis of 1-(alkylamino)-2-(trimethylsilyl)but-3-yne</b> |
| title_full_unstemmed |
<b>Reaction of propargyltrimethylsilane magnesium bromide with aldimines: Synthesis of 1-(alkylamino)-2-(trimethylsilyl)but-3-yne</b> |
| title_sort |
<b>reaction of propargyltrimethylsilane magnesium bromide with aldimines: synthesis of 1-(alkylamino)-2-(trimethylsilyl)but-3-yne</b> |
| publisher |
Chemical Society of Ethiopia |
| series |
Bulletin of the Chemical Society of Ethiopia |
| issn |
1011-3924 1726-801X |
| publishDate |
2002-12-01 |
| description |
The reaction of propargylsilane magnesium bromide with aldimines provides in some cases, an isomeric mixture of three acetylenic amines <b>1</b>, <b>2</b>, <b>3</b> (<b>1</b> and <b>2</b>, as major products). The reaction has great potential and has been exploited for an efficient synthesis of the pure amine <b>2</b>. |
| url |
http://www.ajol.info/index.php/bcse/article/view/20940 |
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