(−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonylimino)]dipropanoate

The title compound, C27H27N3O6, a bis-amide derivative, is also a chiral amino acid ester with l-phenylalanine methyl ester groups as amine substituents. The pyridine ring is oriented at dihedral angles of 89.69 (3) and 62.95 (3)° with respect to the phenyl r...

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Bibliographic Details
Main Authors: Shaohong Yin, Yu Cui, Guangming Xia, Yanju Zhang, Guoxin Sun
Format: Article
Language:English
Published: International Union of Crystallography 2009-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809023721
Description
Summary:The title compound, C27H27N3O6, a bis-amide derivative, is also a chiral amino acid ester with l-phenylalanine methyl ester groups as amine substituents. The pyridine ring is oriented at dihedral angles of 89.69 (3) and 62.95 (3)° with respect to the phenyl rings, while the dihedral angle between the phenyl rings is 60.76 (3)°. In the crystal structure, intermolecular N—H...O hydrogen bonds link the molecules into chains. One of the carbonyl O atoms and one of the methoxy CH3 groups are disordered over two positions. The O atom was refined with occupancies of 0.69 (13) and 0.31 (13), while C and H atoms were refined with occupancies of 0.69 (8) and 0.31 (8).
ISSN:1600-5368