2-Morpholino-4-oxo-4,5-dihydrothiophene-3-carbonitrile

The title compound, C9H10N2O2S, was obtained from the treatment of ethyl 4-cyano-3-hydroxy-5-morpholinothiophene-2-carboxylate with concentrated HCl. The mean plane of the essentially planar dihydrothiophene ring is almost orthogonal to the mirror plane of the N-morpholine substituent, making a dihe...

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Bibliographic Details
Main Authors: JinJiang Zhu, Kevin K. Liu, Matthew A. Marx, Arnold L. Rheingold, Alex Yanovsky
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809041737
Description
Summary:The title compound, C9H10N2O2S, was obtained from the treatment of ethyl 4-cyano-3-hydroxy-5-morpholinothiophene-2-carboxylate with concentrated HCl. The mean plane of the essentially planar dihydrothiophene ring is almost orthogonal to the mirror plane of the N-morpholine substituent, making a dihedral angle of 87.2 (2)°.
ISSN:1600-5368