Microwave Assisted Synthesis of Molybdenum and Tungsten Tetracarbonyl Complexes with a Pyrazolylpyridine Ligand. Crystal structure of cis-[Mo(CO)4{ethyl[3-(2-pyridyl)-1-pyrazolyl]acetate}]

Microwave Assisted Synthesis of Molybdenum and Tungsten Tetracarbonyl Complexes with a Pyrazolylpyridine Ligand. Crystal structure of cis-[Mo(CO)4{ethyl[3-(2-pyridyl)-1-pyrazolyl]acetate}]

We report the one-step syntheses in good yields of the complexes cis-[M(CO)4(pzpy)] {M = Mo, W; pzpy = ethyl[3-(2-pyridyl)-1-pyrazolyl]acetate} directlyfrom the corresponding M(CO)6 starting materials by using microwave-assisted heatingand reaction times of either 30 s (M = Mo) or 15 min (M = W). Th...

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Bibliographic Details
Main Authors: Isabel S. Gonçalves, Martyn Pillinger, Jacek Klinowski, Filipe A. Almeida Paz, Ana C. Coelho
Format: Article
Language:English
Published: MDPI AG 2006-12-01
Series:Molecules
Subjects:
Tetracarbonyl metal complexes
pyrazolylpyridine ligand
microwave synthesis
X-ray structure
Online Access:http://www.mdpi.com/1420-3049/11/12/940/

Internet

http://www.mdpi.com/1420-3049/11/12/940/

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