Synthesis of Activated Carbon Mesoporous from Coffee Waste and Its Application in Adsorption Zinc and Mercury Ions from Aqueous Solution

We obtain activated carbons with high portion of meso pores using coffee residues as precursor for the application of adsorption of large adsorbates. Because of its natural properties, the coffee residue exhibited a large pore size. In this work, the coffee residue were impregnated with ZnCl2 and KO...

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Main Authors: Liliana Giraldo, Juan Carlos Moreno-Piraján
Format: Article
Language:English
Published: Hindawi Limited 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/120763
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spelling doaj-3fd9a4030b9f43ef92b2a703376659da2020-11-24T23:15:51ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102012-01-019293894810.1155/2012/120763Synthesis of Activated Carbon Mesoporous from Coffee Waste and Its Application in Adsorption Zinc and Mercury Ions from Aqueous SolutionLiliana Giraldo0Juan Carlos Moreno-Piraján1Facultad de Ciencias, Departamento de Química, Universidad Nacional de Colombia, Bogotá, ColombiaFacultad de Ciencias, Departamento de Química, Grupo de Investigación en Sólidos Porosos y Calorimetría, Universidad de los Andes, Bogotá, ColombiaWe obtain activated carbons with high portion of meso pores using coffee residues as precursor for the application of adsorption of large adsorbates. Because of its natural properties, the coffee residue exhibited a large pore size. In this work, the coffee residue were impregnated with ZnCl2 and KOH, and then carbonized under the nitrogen conditions and activated with CO2 respectively. Obtained activated carbons are used in the adsorption of ions Hg(II) and Zn(II). These adsorbents are efficacious to remove these ions from aqueous solution, with monocomponent equilibrium adsorption capacities ranging from from 0.002 to 0.380 mmol∙g-1 for Hg on ACK3 and from 0.002 to 0.330 mmol∙g-1 for ACZ3. For Zn(II) on ACK2 from 0.002 to 0.300 mmol∙g-1, and from 0.001 to 0.274 mmol∙g-1 for ACZ2.http://dx.doi.org/10.1155/2012/120763
collection DOAJ
language English
format Article
sources DOAJ
author Liliana Giraldo
Juan Carlos Moreno-Piraján
spellingShingle Liliana Giraldo
Juan Carlos Moreno-Piraján
Synthesis of Activated Carbon Mesoporous from Coffee Waste and Its Application in Adsorption Zinc and Mercury Ions from Aqueous Solution
E-Journal of Chemistry
author_facet Liliana Giraldo
Juan Carlos Moreno-Piraján
author_sort Liliana Giraldo
title Synthesis of Activated Carbon Mesoporous from Coffee Waste and Its Application in Adsorption Zinc and Mercury Ions from Aqueous Solution
title_short Synthesis of Activated Carbon Mesoporous from Coffee Waste and Its Application in Adsorption Zinc and Mercury Ions from Aqueous Solution
title_full Synthesis of Activated Carbon Mesoporous from Coffee Waste and Its Application in Adsorption Zinc and Mercury Ions from Aqueous Solution
title_fullStr Synthesis of Activated Carbon Mesoporous from Coffee Waste and Its Application in Adsorption Zinc and Mercury Ions from Aqueous Solution
title_full_unstemmed Synthesis of Activated Carbon Mesoporous from Coffee Waste and Its Application in Adsorption Zinc and Mercury Ions from Aqueous Solution
title_sort synthesis of activated carbon mesoporous from coffee waste and its application in adsorption zinc and mercury ions from aqueous solution
publisher Hindawi Limited
series E-Journal of Chemistry
issn 0973-4945
2090-9810
publishDate 2012-01-01
description We obtain activated carbons with high portion of meso pores using coffee residues as precursor for the application of adsorption of large adsorbates. Because of its natural properties, the coffee residue exhibited a large pore size. In this work, the coffee residue were impregnated with ZnCl2 and KOH, and then carbonized under the nitrogen conditions and activated with CO2 respectively. Obtained activated carbons are used in the adsorption of ions Hg(II) and Zn(II). These adsorbents are efficacious to remove these ions from aqueous solution, with monocomponent equilibrium adsorption capacities ranging from from 0.002 to 0.380 mmol∙g-1 for Hg on ACK3 and from 0.002 to 0.330 mmol∙g-1 for ACZ3. For Zn(II) on ACK2 from 0.002 to 0.300 mmol∙g-1, and from 0.001 to 0.274 mmol∙g-1 for ACZ2.
url http://dx.doi.org/10.1155/2012/120763
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