Crystal structure of poly[(2,2′-bipyridine-κ2N,N′)tetra-μ2-cyanido-κ4C:N;κ4N:C-manganese(II)disilver(I)]
The title compound, [Ag2Mn(CN)4(C10H8N2)]n or Mn(bipy){Ag(CN)2}2 (bipy = 2,2′-bipyridine) is isostructural with Cd(bipy){Au(CN)2}2 [Guo et al. (2009). CrystEngComm, 11, 61–66]. The MnII atom has crystallographically imposed twofold symmetry and a distorted octahedral coordination sphere consisting o...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2015-10-01
|
| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S205698901501676X |
| Summary: | The title compound, [Ag2Mn(CN)4(C10H8N2)]n or Mn(bipy){Ag(CN)2}2 (bipy = 2,2′-bipyridine) is isostructural with Cd(bipy){Au(CN)2}2 [Guo et al. (2009). CrystEngComm, 11, 61–66]. The MnII atom has crystallographically imposed twofold symmetry and a distorted octahedral coordination sphere consisting of six N atoms from one bipyridine ligand and four dicyanoargentate(I) anions, [Ag(CN)2]−, while the AgI atom of the complex anion displays the expected linear geometry. Each [Ag(CN)2]− unit connects to two neighbouring [Mn(bipy)]2+ cations to give an threefold interpenetrating quartz-like three-dimensional framework. No directional interactions beyond van der Waals contacts are observed. |
|---|---|
| ISSN: | 2056-9890 |