Hydrogenation of levulinic acid using Ru-containing catalysts based on hypercrosslinked polystyrene

This work is devoted to the investigation of the possibility of the use of Ru-containing catalysts on the basis of polymeric matrix of hypercrosslinked polystyrene (HPS) in the hydrogenation of levulinic acid (LA) to gamma-valerolactone (GVL). HPS-based Ru-containing catalysts were synthesized at va...

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Main Authors:	Protsenko Igor I., Nikoshvili Linda Zh., Bykov Alexey V., Matveeva Valentina G., Sulman Alexandrina, Sulman Esther M., Rebrov Evgeny V.
Format:	Article
Language:	English
Published:	De Gruyter 2017-05-01
Series:	Green Processing and Synthesis
Subjects:	gamma-valerolactone hydrogenation hypercrosslinked polystyrene levulinic acid ruthenium nanoparticles
Online Access:	https://doi.org/10.1515/gps-2016-0189

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spelling	doaj-3fd147a274ca49c8867b63d1b88b42db2021-10-02T19:16:48ZengDe GruyterGreen Processing and Synthesis2191-95422191-95502017-05-016328128610.1515/gps-2016-0189Hydrogenation of levulinic acid using Ru-containing catalysts based on hypercrosslinked polystyreneProtsenko Igor I.0Nikoshvili Linda Zh.1Bykov Alexey V.2Matveeva Valentina G.3Sulman Alexandrina4Sulman Esther M.5Rebrov Evgeny V.6Department of Biotechnology and Chemistry, Tver Technical University, A. Nikitina str. 22, 170026Tver, RussiaDepartment of Biotechnology and Chemistry, Tver Technical University, A. Nikitina str. 22, 170026 Tver, Russia, Tel.: +74822789348, Fax: +74822789317Department of Biotechnology and Chemistry, Tver Technical University, A. Nikitina str. 22, 170026Tver, RussiaDepartment of Biotechnology and Chemistry, Tver Technical University, A. Nikitina str. 22, 170026Tver, RussiaDepartment of Biotechnology and Chemistry, Tver Technical University, A. Nikitina str. 22, 170026Tver, RussiaDepartment of Biotechnology and Chemistry, Tver Technical University, A. Nikitina str. 22, 170026Tver, RussiaDepartment of Biotechnology and Chemistry, Tver Technical University, A. Nikitina str. 22, 170026Tver, RussiaThis work is devoted to the investigation of the possibility of the use of Ru-containing catalysts on the basis of polymeric matrix of hypercrosslinked polystyrene (HPS) in the hydrogenation of levulinic acid (LA) to gamma-valerolactone (GVL). HPS-based Ru-containing catalysts were synthesized at variation of HPS type (MN100 bearing amino groups or MN270 without functional groups) and metal content. Catalyst 5%-Ru/MN100 was shown to compete with commercial 5%-Ru/C and to allow carrying out the hydrogenation of LA in aqueous medium with high yields of GVL (more than 99%).https://doi.org/10.1515/gps-2016-0189gamma-valerolactonehydrogenationhypercrosslinked polystyrenelevulinic acidruthenium nanoparticles
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Protsenko Igor I. Nikoshvili Linda Zh. Bykov Alexey V. Matveeva Valentina G. Sulman Alexandrina Sulman Esther M. Rebrov Evgeny V.
spellingShingle	Protsenko Igor I. Nikoshvili Linda Zh. Bykov Alexey V. Matveeva Valentina G. Sulman Alexandrina Sulman Esther M. Rebrov Evgeny V. Hydrogenation of levulinic acid using Ru-containing catalysts based on hypercrosslinked polystyrene Green Processing and Synthesis gamma-valerolactone hydrogenation hypercrosslinked polystyrene levulinic acid ruthenium nanoparticles
author_facet	Protsenko Igor I. Nikoshvili Linda Zh. Bykov Alexey V. Matveeva Valentina G. Sulman Alexandrina Sulman Esther M. Rebrov Evgeny V.
author_sort	Protsenko Igor I.
title	Hydrogenation of levulinic acid using Ru-containing catalysts based on hypercrosslinked polystyrene
title_short	Hydrogenation of levulinic acid using Ru-containing catalysts based on hypercrosslinked polystyrene
title_full	Hydrogenation of levulinic acid using Ru-containing catalysts based on hypercrosslinked polystyrene
title_fullStr	Hydrogenation of levulinic acid using Ru-containing catalysts based on hypercrosslinked polystyrene
title_full_unstemmed	Hydrogenation of levulinic acid using Ru-containing catalysts based on hypercrosslinked polystyrene
title_sort	hydrogenation of levulinic acid using ru-containing catalysts based on hypercrosslinked polystyrene
publisher	De Gruyter
series	Green Processing and Synthesis
issn	2191-9542 2191-9550
publishDate	2017-05-01
description	This work is devoted to the investigation of the possibility of the use of Ru-containing catalysts on the basis of polymeric matrix of hypercrosslinked polystyrene (HPS) in the hydrogenation of levulinic acid (LA) to gamma-valerolactone (GVL). HPS-based Ru-containing catalysts were synthesized at variation of HPS type (MN100 bearing amino groups or MN270 without functional groups) and metal content. Catalyst 5%-Ru/MN100 was shown to compete with commercial 5%-Ru/C and to allow carrying out the hydrogenation of LA in aqueous medium with high yields of GVL (more than 99%).
topic	gamma-valerolactone hydrogenation hypercrosslinked polystyrene levulinic acid ruthenium nanoparticles
url	https://doi.org/10.1515/gps-2016-0189
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Hydrogenation of levulinic acid using Ru-containing catalysts based on hypercrosslinked polystyrene

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