Dichlorido(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)gold(III) tetrachloridoaurate(III)

In the cation of the title compound, [AuCl2(C24H16N2)][AuCl4], the AuIII atom is four-coordinated in a distorted square-planar configuration by two N atoms from a 4,7-diphenyl-1,10-phenanthroline ligand and two terminal Cl atoms. In the anion, the AuIII atom has a square-planar coordination. In the...

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Bibliographic Details
Main Authors: Hamid Reza Khavasi, Vahid Amani, Roya Ahmadi
Format: Article
Language:English
Published: International Union of Crystallography 2008-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808025476
Description
Summary:In the cation of the title compound, [AuCl2(C24H16N2)][AuCl4], the AuIII atom is four-coordinated in a distorted square-planar configuration by two N atoms from a 4,7-diphenyl-1,10-phenanthroline ligand and two terminal Cl atoms. In the anion, the AuIII atom has a square-planar coordination. In the crystal structure, intra- and intermolecular C—H...Cl hydrogen bonds are found.
ISSN:1600-5368