Chiral Ag23 nanocluster with open shell electronic structure and helical face-centered cubic framework

Chiral noble metal nanostructures are particularly interesting for optical materials and enantioselective catalysis. Here, the authors report the synthesis and crystal structure of a chiral Ag23 nanocluster, whose twisted fcc skeleton is responsible for its chiral nature–an unusual property for silv...

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Main Authors:	Chao Liu, Tao Li, Hadi Abroshan, Zhimin Li, Chen Zhang, Hyung J. Kim, Gao Li, Rongchao Jin
Format:	Article
Language:	English
Published:	Nature Publishing Group 2018-02-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-018-03136-9

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spelling	doaj-3fa8ce4130f44f09adf26f681cbb88672021-05-11T09:29:59ZengNature Publishing GroupNature Communications2041-17232018-02-01911610.1038/s41467-018-03136-9Chiral Ag23 nanocluster with open shell electronic structure and helical face-centered cubic frameworkChao Liu0Tao Li1Hadi Abroshan2Zhimin Li3Chen Zhang4Hyung J. Kim5Gao Li6Rongchao Jin7State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of SciencesSchool of Physical Science and Technology, ShanghaiTech UniversityDepartment of Chemistry, Carnegie Mellon UniversityState Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of SciencesDepartment of Chemistry, University of Missouri-ColumbiaDepartment of Chemistry, Carnegie Mellon UniversityState Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of SciencesDepartment of Chemistry, Carnegie Mellon UniversityChiral noble metal nanostructures are particularly interesting for optical materials and enantioselective catalysis. Here, the authors report the synthesis and crystal structure of a chiral Ag23 nanocluster, whose twisted fcc skeleton is responsible for its chiral nature–an unusual property for silver.https://doi.org/10.1038/s41467-018-03136-9
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Chao Liu Tao Li Hadi Abroshan Zhimin Li Chen Zhang Hyung J. Kim Gao Li Rongchao Jin
spellingShingle	Chao Liu Tao Li Hadi Abroshan Zhimin Li Chen Zhang Hyung J. Kim Gao Li Rongchao Jin Chiral Ag23 nanocluster with open shell electronic structure and helical face-centered cubic framework Nature Communications
author_facet	Chao Liu Tao Li Hadi Abroshan Zhimin Li Chen Zhang Hyung J. Kim Gao Li Rongchao Jin
author_sort	Chao Liu
title	Chiral Ag23 nanocluster with open shell electronic structure and helical face-centered cubic framework
title_short	Chiral Ag23 nanocluster with open shell electronic structure and helical face-centered cubic framework
title_full	Chiral Ag23 nanocluster with open shell electronic structure and helical face-centered cubic framework
title_fullStr	Chiral Ag23 nanocluster with open shell electronic structure and helical face-centered cubic framework
title_full_unstemmed	Chiral Ag23 nanocluster with open shell electronic structure and helical face-centered cubic framework
title_sort	chiral ag23 nanocluster with open shell electronic structure and helical face-centered cubic framework
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2018-02-01
description	Chiral noble metal nanostructures are particularly interesting for optical materials and enantioselective catalysis. Here, the authors report the synthesis and crystal structure of a chiral Ag23 nanocluster, whose twisted fcc skeleton is responsible for its chiral nature–an unusual property for silver.
url	https://doi.org/10.1038/s41467-018-03136-9
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Chiral Ag23 nanocluster with open shell electronic structure and helical face-centered cubic framework

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