(4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methanesulfonate

(4-Benzyl-2-oxo-1,3-oxazolidin-5-yl)methyl methanesulfonate

The title compound, C12H15NO5S, features an approximately planar five-membered oxazolidin ring (r.m.s. deviation = 0.045 Å) with the peripheral benzyl and methyl methanesulfonate residues lying to either side of the plane. In the crystal, N—H...O hydrogen bon...

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Bibliographic Details
Main Authors: Wilson Cunico, Claudia R. B. Gomes, Edward R. T. Tiekink, Walcimar T. Vellasco Junior, James L. Wardell, Solange M. S. V. Wardell
Format: Article
Language:English
Published: International Union of Crystallography 2010-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809055020
Description
Summary:The title compound, C12H15NO5S, features an approximately planar five-membered oxazolidin ring (r.m.s. deviation = 0.045 Å) with the peripheral benzyl and methyl methanesulfonate residues lying to either side of the plane. In the crystal, N—H...O hydrogen bonds, involving one of the sulfur-bound oxo groups as acceptor, lead to the formation of supramolecular chains along the b axis. These chains are reinforced by C—H...O contacts with the carbonyl O atom accepting three such interactions. The structure was refined as a racemic twin, with the major component being present 89% of the time.
ISSN:1600-5368

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