(Z)-3-(4-Chlorophenyl)-2-{[N-(2-formylphenyl)-4-methylbenzenesulfonamido]methyl}prop-2-enenitrile
In the title compound, C24H19ClN2O3S, the sulfonyl-bound benzene ring forms dihedral angles of 38.1 (2) and 81.2 (1)°, respectively, with the formyl benzene and benzene rings. The molecular conformation is stabilized by a weak intramolecular C—H...
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International Union of Crystallography
2012-01-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681105241X |
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doaj-3f97d62a2cbe447ab57dba68e38bee792020-11-25T01:04:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681o56o5710.1107/S160053681105241X(Z)-3-(4-Chlorophenyl)-2-{[N-(2-formylphenyl)-4-methylbenzenesulfonamido]methyl}prop-2-enenitrileR. MadhanrajS. MurugavelD. KannanM. BakthadossIn the title compound, C24H19ClN2O3S, the sulfonyl-bound benzene ring forms dihedral angles of 38.1 (2) and 81.2 (1)°, respectively, with the formyl benzene and benzene rings. The molecular conformation is stabilized by a weak intramolecular C—H...O hydrogen bond, which generates an S(5) ring motif. The crystal packing is stabilized by C—H...O hydrogen bonds, which generate C(7) zigzag chains along [010] and R33(19) ring motifs along [010]. The crystal packing is further stabilized by C—Cl...π interactions [Cl...centroid = 3.456 (2) Å and C—Cl...centroid = 173.4 (2)°].http://scripts.iucr.org/cgi-bin/paper?S160053681105241X |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
R. Madhanraj S. Murugavel D. Kannan M. Bakthadoss |
spellingShingle |
R. Madhanraj S. Murugavel D. Kannan M. Bakthadoss (Z)-3-(4-Chlorophenyl)-2-{[N-(2-formylphenyl)-4-methylbenzenesulfonamido]methyl}prop-2-enenitrile Acta Crystallographica Section E |
author_facet |
R. Madhanraj S. Murugavel D. Kannan M. Bakthadoss |
author_sort |
R. Madhanraj |
title |
(Z)-3-(4-Chlorophenyl)-2-{[N-(2-formylphenyl)-4-methylbenzenesulfonamido]methyl}prop-2-enenitrile |
title_short |
(Z)-3-(4-Chlorophenyl)-2-{[N-(2-formylphenyl)-4-methylbenzenesulfonamido]methyl}prop-2-enenitrile |
title_full |
(Z)-3-(4-Chlorophenyl)-2-{[N-(2-formylphenyl)-4-methylbenzenesulfonamido]methyl}prop-2-enenitrile |
title_fullStr |
(Z)-3-(4-Chlorophenyl)-2-{[N-(2-formylphenyl)-4-methylbenzenesulfonamido]methyl}prop-2-enenitrile |
title_full_unstemmed |
(Z)-3-(4-Chlorophenyl)-2-{[N-(2-formylphenyl)-4-methylbenzenesulfonamido]methyl}prop-2-enenitrile |
title_sort |
(z)-3-(4-chlorophenyl)-2-{[n-(2-formylphenyl)-4-methylbenzenesulfonamido]methyl}prop-2-enenitrile |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2012-01-01 |
description |
In the title compound, C24H19ClN2O3S, the sulfonyl-bound benzene ring forms dihedral angles of 38.1 (2) and 81.2 (1)°, respectively, with the formyl benzene and benzene rings. The molecular conformation is stabilized by a weak intramolecular C—H...O hydrogen bond, which generates an S(5) ring motif. The crystal packing is stabilized by C—H...O hydrogen bonds, which generate C(7) zigzag chains along [010] and R33(19) ring motifs along [010]. The crystal packing is further stabilized by C—Cl...π interactions [Cl...centroid = 3.456 (2) Å and C—Cl...centroid = 173.4 (2)°]. |
url |
http://scripts.iucr.org/cgi-bin/paper?S160053681105241X |
work_keys_str_mv |
AT rmadhanraj z34chlorophenyl2n2formylphenyl4methylbenzenesulfonamidomethylprop2enenitrile AT smurugavel z34chlorophenyl2n2formylphenyl4methylbenzenesulfonamidomethylprop2enenitrile AT dkannan z34chlorophenyl2n2formylphenyl4methylbenzenesulfonamidomethylprop2enenitrile AT mbakthadoss z34chlorophenyl2n2formylphenyl4methylbenzenesulfonamidomethylprop2enenitrile |
_version_ |
1725196372357939200 |