(Z)-3-(4-Chlorophenyl)-2-{[N-(2-formylphenyl)-4-methylbenzenesulfonamido]methyl}prop-2-enenitrile

In the title compound, C24H19ClN2O3S, the sulfonyl-bound benzene ring forms dihedral angles of 38.1 (2) and 81.2 (1)°, respectively, with the formyl benzene and benzene rings. The molecular conformation is stabilized by a weak intramolecular C—H...

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Bibliographic Details
Main Authors: R. Madhanraj, S. Murugavel, D. Kannan, M. Bakthadoss
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681105241X
Description
Summary:In the title compound, C24H19ClN2O3S, the sulfonyl-bound benzene ring forms dihedral angles of 38.1 (2) and 81.2 (1)°, respectively, with the formyl benzene and benzene rings. The molecular conformation is stabilized by a weak intramolecular C—H...O hydrogen bond, which generates an S(5) ring motif. The crystal packing is stabilized by C—H...O hydrogen bonds, which generate C(7) zigzag chains along [010] and R33(19) ring motifs along [010]. The crystal packing is further stabilized by C—Cl...π interactions [Cl...centroid = 3.456 (2) Å and C—Cl...centroid = 173.4 (2)°].
ISSN:1600-5368