(Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol

(Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol

Enantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H2O employing H2O2 as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e. values...

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Main Authors: Francesco Paolo Ballistreri, Chiara M. A. Gangemi, Andrea Pappalardo, Gaetano A. Tomaselli, Rosa Maria Toscano, Giuseppe Trusso Sfrazzetto
Format: Article
Language:English
Published: MDPI AG 2016-07-01
Series:International Journal of Molecular Sciences
Subjects:
epoxidation
enantioselectivity
jacobsen catalyst
hydrogen peroxide
water
Online Access:http://www.mdpi.com/1422-0067/17/7/1112
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spelling doaj-3ee9838a07194c5a947685d7457339252020-11-24T20:49:03ZengMDPI AGInternational Journal of Molecular Sciences1422-00672016-07-01177111210.3390/ijms17071112ijms17071112(Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green ProtocolFrancesco Paolo Ballistreri0Chiara M. A. Gangemi1Andrea Pappalardo2Gaetano A. Tomaselli3Rosa Maria Toscano4Giuseppe Trusso Sfrazzetto5Department of Chemical Sciences, University of Catania, Viale Andrea Doria 6, 95125 Catania, ItalyDepartment of Chemical Sciences, University of Catania, Viale Andrea Doria 6, 95125 Catania, ItalyDepartment of Chemical Sciences, University of Catania, Viale Andrea Doria 6, 95125 Catania, ItalyDepartment of Chemical Sciences, University of Catania, Viale Andrea Doria 6, 95125 Catania, ItalyDepartment of Chemical Sciences, University of Catania, Viale Andrea Doria 6, 95125 Catania, ItalyDepartment of Chemical Sciences, University of Catania, Viale Andrea Doria 6, 95125 Catania, ItalyEnantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H2O employing H2O2 as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e. values ranging from good to excellent (up to 95%).http://www.mdpi.com/1422-0067/17/7/1112epoxidationenantioselectivityjacobsen catalysthydrogen peroxidewater
collection DOAJ
language English
format Article
sources DOAJ
author Francesco Paolo Ballistreri
Chiara M. A. Gangemi
Andrea Pappalardo
Gaetano A. Tomaselli
Rosa Maria Toscano
Giuseppe Trusso Sfrazzetto
spellingShingle Francesco Paolo Ballistreri
Chiara M. A. Gangemi
Andrea Pappalardo
Gaetano A. Tomaselli
Rosa Maria Toscano
Giuseppe Trusso Sfrazzetto
(Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol
International Journal of Molecular Sciences
epoxidation
enantioselectivity
jacobsen catalyst
hydrogen peroxide
water
author_facet Francesco Paolo Ballistreri
Chiara M. A. Gangemi
Andrea Pappalardo
Gaetano A. Tomaselli
Rosa Maria Toscano
Giuseppe Trusso Sfrazzetto
author_sort Francesco Paolo Ballistreri
title (Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol
title_short (Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol
title_full (Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol
title_fullStr (Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol
title_full_unstemmed (Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol
title_sort (salen)mn(iii) catalyzed asymmetric epoxidation reactions by hydrogen peroxide in water: a green protocol
publisher MDPI AG
series International Journal of Molecular Sciences
issn 1422-0067
publishDate 2016-07-01
description Enantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H2O employing H2O2 as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e. values ranging from good to excellent (up to 95%).
topic epoxidation
enantioselectivity
jacobsen catalyst
hydrogen peroxide
water
url http://www.mdpi.com/1422-0067/17/7/1112
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